Volume 14 Issue 2
Mar.  2021
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Chinese Optics  > 2021  >  14(2): 418-430.
WANG Dan, XUE Bin, TU Lang-ping, ZHANG You-lin, SONG Jun, QU Jun-le, KONG Xiang-gui. Enhanced dye-sensitized up-conversion luminescence of neodymium-sensitized multi-shell nanostructures[J]. Chinese Optics, 2021, 14(2): 418-430. doi: 10.37188/CO.2020-0097
Citation: WANG Dan, XUE Bin, TU Lang-ping, ZHANG You-lin, SONG Jun, QU Jun-le, KONG Xiang-gui. Enhanced dye-sensitized up-conversion luminescence of neodymium-sensitized multi-shell nanostructures[J]. Chinese Optics, 2021, 14(2): 418-430. doi: 10.37188/CO.2020-0097
shu

Enhanced dye-sensitized up-conversion luminescence of neodymium-sensitized multi-shell nanostructures

  • 1.

    Key Laboratory of Optoelectronic Devices and Systems of the Ministry of Education/Guangdong Province, College of Physics and Optoelectronic Engineering, Shenzhen University, Shenzhen 518060, China

  • 2.

    College of Information Engineering, Shenzhen University, Shenzhen 518060, China

  • 3.

    State Key Laboratory of Luminescence and Applications, Changchun Institute of Optics, Fine Mechanics and Physics, Chinese Academy of Sciences, Changchun 130033, China

Funds:  Supported by National Key R&D Program of China (No. 2018YFC0910602); National Natural Science Foundation of China (No. 61605130, No. 11604331, No. 61775145, No. 61835009); Project of Science and Technology Agency, Jilin Province (No. 20180101222JC); Shenzhen Basic Research Project (No. JCYJ20180305125425815)
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  • Author Bio:

    WANG Dan (1986—), female, born in Songyuan City, Jilin province. She is a doctor and postdoctor. In 2015, she received her doctorate from the Changchun Institute of Optics, Fine Mechanics and Physics, Chinese Academy of Sciences. She is mainly engaged in the design of luminescent materials, the bio-functionalization of nanomaterials, and the application of biological photonics and nano-biomedicine. E-mail: wangdan66322@163.com

    KONG Xiang-gui (1955—), male, born in Qufu City, Shandong Province. He is a doctor, researcher and doctoral supervisor. He received his bachelor’s degree from the University of Science and Technology of China in 1980 and his doctor’s degree from the Changchun Institute of Optics, Fine Mechanics and Physics, Chinese Academy of Sciences in 1998. He is currently a director of the Biophysical Society of China, mainly engaged in the research on the application of biomedical imaging, photodynamic therapy and luminescent nanomaterials in biomedicine. E-mail: xgkong14@ciomp.ac.cn

  • Corresponding author: songjun@szu.edu.cn; xgkong14@ciomp.ac.cn
  • Received Date: 25 May 2020
  • Rev Recd Date: 24 Jun 2020
    • Available Online: 02 Feb 2021
  • Publish Date: 23 Mar 2021
    Abstract
  • Lanthanide-ion-doped upconversion luminescence is limited by the small absorption cross-section and narrow absorption band of lanthanide ions, which results in weak luminescence. Recently, a dye-sensitized method has proven to be an effective strategy of increasing upconversion luminescence. However, simply attaching dye molecules to nanoparticles with classic Yb-doped nanostructures cannot effectively activate the sensitizing ability of the dye molecules. In response to this problem, we designed Nd-sensitized core/shell/shell (NaYF4:Yb/Er (20/2%)@ NaYF4:Yb (10 %)@ NaYF4:Nd (80 %)) nanostructures, compared with the classic IR-806 sensitized NaYF4:Yb/Er nanostructure, their upconversion luminescence (500 to 700 nm) was approximately enhanced by a factor of 38. Through analysis of the nanostructure’s emission and luminescence lifetime data, the enhancement was confirmed by the effective overlap of Nd absorption with the emission of near-infrared dye molecules and the protective effects of the shell structure on the luminescent center (the lifetime of Er (4S3/2→4I15/2) was increased by 1.7 times). In addition, we found that the doping Yb3+ in the outermost layer will decrease the dye-sensitized luminescence intensity. Furthermore, this Nd-sensitized core/shell/shell structure also achieved enhancement in the sensitized upconversion luminescence of the luminescence centers of Ho and Tm, which establishes a foundation for enhanced dye-sensitized upconversion luminescence.

     

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    • References(24)
  • [1]
    AUZEL F. Upconversion and anti-stokes processes with f and d ions in solids[J]. Chemical Reviews, 2004, 104(1): 139-174. doi: 10.1021/cr020357g
    [2]
    LI X X, LI Y Q, WANG X, et al. Highly sensitive down-conversion optical temperature-measurement material: NaGd(WO4)2:Yb3+/Er3 +[J]. Chinese Optics, 2019, 12(3): 596-605. (in Chinese) doi: 10.3788/co.20191203.0596
    [3]
    HE F, GAI SH L, YANG P P, et al. Luminescence modification and application of the lanthanide upconversion fluorescence materials[J]. Chinese Journal of Luminescence, 2018, 39(1): 92-106. (in Chinese) doi: 10.3788/fgxb20183901.0092
    [4]
    WANG F, WEN SH H, HE H, et al. Microscopic inspection and tracking of single upconversion nanoparticles in living cells[J]. Light:Science &Applications, 2018, 7(4): e18007.
    [5]
    CHEN SH, WEITEMIER A Z, ZENG X, et al. Near-infrared deep brain stimulation via upconversion nanoparticle-mediated optogenetics[J]. Science, 2018, 359(6376): 679-684.
    [6]
    LIU Y J, LU Y Q, YANG X S, et al. Amplified stimulated emission in upconversion nanoparticles for super-resolution nanoscopy[J]. Nature, 2017, 543(7644): 229-233. doi: 10.1038/nature21366
    [7]
    WANG D, XUE B, OHULCHANSKYY T Y, et al. Inhibiting tumor oxygen metabolism and simultaneously generating oxygen by intelligent upconversion nanotherapeutics for enhanced photodynamic therapy[J]. Biomaterials, 2020, 251: 120088. doi: 10.1016/j.biomaterials.2020.120088
    [8]
    XUE B, WANG D, ZHANG Y L, et al. Regulating the color output and simultaneously enhancing the intensity of upconversion nanoparticles via a dye sensitization strategy[J]. Journal of Materials Chemistry C, 2019, 7(28): 8607-8615. doi: 10.1039/C9TC02293G
    [9]
    TU L P, LIU X M, WU F, et al. Excitation energy migration dynamics in upconversion nanomaterials[J]. Chemical Society Reviews, 2015, 44(6): 1331-1345. doi: 10.1039/C4CS00168K
    [10]
    XU W, CHEN X, SONG H W. Manipulation of local electromagnetic field in upconversion luminescence of rare earth ions[J]. Chinese Journal of Luminescence, 2018, 39(1): 1-26. (in Chinese) doi: 10.3788/fgxb20183901.0001
    [11]
    ZOU W Q, VISSER C, MADURO J A, et al. Broadband dye-sensitized upconversion of near-infrared light[J]. Nature Photonics, 2012, 6(8): 560-564. doi: 10.1038/nphoton.2012.158
    [12]
    CHEN G Y, DAMASCO J, QIU H L, et al. Energy-cascaded upconversion in an organic dye-sensitized core/shell fluoride nanocrystal[J]. Nano Letters, 2015, 15(11): 7400-7407. doi: 10.1021/acs.nanolett.5b02830
    [13]
    WANG D, WANG D, KUZMIN A, et al. ICG-sensitized NaYF4:Er nanostructure for theranostics[J]. Advanced Optical Materials, 2018, 6(12): 1701142. doi: 10.1002/adom.201701142
    [14]
    WANG D, XUE B, KONG X G, et al. 808 nm driven Nd3+-sensitized upconversion nanostructures for photodynamic therapy and simultaneous fluorescence imaging[J]. Nanoscale, 2015, 7(1): 190-197. doi: 10.1039/C4NR04953E
    [15]
    WANG D, XUE B, SONG J, et al. Compressed energy transfer distance for remarkable enhancement of the luminescence of Nd3+-sensitized upconversion nanoparticles[J]. Journal of Materials Chemistry C, 2018, 6(24): 6597-6604. doi: 10.1039/C8TC00936H
    [16]
    ZHONG Y T, TIAN G, GU Z J, et al. Elimination of photon quenching by a transition layer to fabricate a quenching-shield sandwich structure for 800 nm excited upconversion luminescence of Nd3+ -sensitized nanoparticles[J]. Advanced Materials, 2014, 26(18): 2831-2837. doi: 10.1002/adma.201304903
    [17]
    XUE B, WANG D, TU L P, et al. Ultrastrong absorption meets ultraweak absorption: unraveling the energy-dissipative routes for dye-sensitized upconversion luminescence[J]. Journal of Physical Chemistry Letters, 2018, 9(16): 4625-4631. doi: 10.1021/acs.jpclett.8b01931
    [18]
    LI J, LIU L, GUO H Q, et al. An upconversion fluorescent method for rapid detection of perfluorooctane sulfonate in water samples based on fluorine- fluorine interaction[J]. Chinese Journal of Analytical Chemistry, 2019, 47(3): 380-387. (in Chinese)
    [19]
    SHAO SH, DING B B, ZHU ZH L, et al. Preparation of water-soluble up-conversion nano-drug by host-guest chemistry and its application in tumor diagnosis and treatment[J]. Chinese Journal of Analytical Chemistry, 2019, 47(6): 823-831. (in Chinese)
    [20]
    CUI L, ZHAO M H, ZHANG CH Y. Recent advance in applications of host-guest interaction in biochemical analysis[J]. Chinese Journal of Analytical Chemistry, 2020, 48(7): 817-826. (in Chinese)
    [21]
    MENG ZH P, WU S L. Manipulating upconversion luminescence of rare earth by photonic crystals[J]. Chinese Journal of Luminescence, 2020, 41(8): 913-925. (in Chinese) doi: 10.37188/fgxb20204108.0913
    [22]
    SUN J F, YAN D, LIU L. Three-primary-color upconversion in single lanthanide based nanoparticle[J]. Chinese Journal of Luminescence, 2020, 41(1): 1-8. (in Chinese) doi: 10.3788/fgxb20204101.0001
    [23]
    YU H Y, TU L P, ZHANG Y L, et al. Quantitative analysis of the surface quenching effect of lanthanide-doped upconversion nanoparticles in solvents[J]. Chinese Optics, 2019, 12(6): 1288-1294. (in Chinese) doi: 10.3788/co.20191206.1288
    [24]
    FISCHER S, BRONSTEIN N D, SWABECK J K, et al. Precise tuning of surface quenching for luminescence enhancement in core-shell lanthanide-doped nanocrystals[J]. Nano Letters, 2016, 16(11): 7241-7247. doi: 10.1021/acs.nanolett.6b03683
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