Volume 4 Issue 6
Dec.  2011
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KU Shin-an, CHU Wei-chen, LUO Chih-wei, ANDREEV Y M, LANSKII G V, SHAIDUKO A V, IZAAK T I, SVETLICHNYI V A, VAYTULEVICH E A, ZUEV V V. Optical properties of Te-doped GaSe crystal[J]. Chinese Optics, 2011, 4(6): 660-666.
Citation: KU Shin-an, CHU Wei-chen, LUO Chih-wei, ANDREEV Y M, LANSKII G V, SHAIDUKO A V, IZAAK T I, SVETLICHNYI V A, VAYTULEVICH E A, ZUEV V V. Optical properties of Te-doped GaSe crystal[J]. Chinese Optics, 2011, 4(6): 660-666.

Optical properties of Te-doped GaSe crystal

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supported by RFBR Project(No.10-02-01452-a), Presidium SB RAS under the Project VII.63.3.1 of VII.63.3 Prog. and Join Proj. between Presidium SB RAS and Presidium NAS, Belarus No.10 of 2010.

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  • Author Bio:

    KU Shin-an(1985-), Post-graduate student, National Chiao Tung University, Taiwan, China. His research interests include nonlinear optics and THz spectroscopy. E-mail:ksa7471@hotmail.com CHU Wei-chen(1989-), Master Student, National Chiao Tung University, Taiwan, China. Her research interests include nonlinear optics and THz spectroscopy. E-mail:s.daffodil@hotmail.com

    KU Shin-an(1985-), Post-graduate student, National Chiao Tung University, Taiwan, China. His research interests include nonlinear optics and THz spectroscopy. E-mail:ksa7471@hotmail.com CHU Wei-chen(1989-), Master Student, National Chiao Tung University, Taiwan, China. Her research interests include nonlinear optics and THz spectroscopy. E-mail:s.daffodil@hotmail.com

  • Received Date: 21 Sep 2011
  • Rev Recd Date: 23 Nov 2011
  • Publish Date: 25 Dec 2011
  • -GaSe crystals are grown with the stoichiometric GaSe of 0.05%, 0.1%, 0.5%, 1% and 2%(mass percent) Te and are characterized by GaSe∶Te(0.01%, 0.07%, 0.38%, 0.67% and 2.07%(mass percent)) crystals. The transformation of the rigid layer phonon modes with doping is studied for the first time. The absorption peak of the rigid mode E'(2) centered at ~0.59 THz is rising up in the intensity till reaching a maximal value on the first stage of the doping concentration less than 0.38%(mass percent). This process correlates well with the improvement in the optical property. Further doping is resulting in the decrease of the intensity till vanishing the E'(2) absorption peak at 1%(mass percent) Te. Simultaneously with the E'(2) absorption peak decreasing, the absorption peak of the rigid mode E'(2) centered at 1.78 THz is rising up in the intensity. The two processes correlate well with the degradation in the optical quality of GaSe∶Te crystal. The doping level that results in the highest intensity of the absorption peak of the rigid layer mode E'(2) is proposed as a criterion in the identification of the optimal Te-doping in GaSe crystal that is confirmed by THz generation via optical rectification.

     

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  • [1] DMITRIEV V G,GURZADYAN G G,NIKOGOSYAN D N. Handbook for Nonlinear Optical Crystals[M]. 3rd ed. Berlin:Springer,1999. [2] LEE Y S. Principles of Terahertz Science and Technology[M]. Berlin:Springer,2008. [3] ALLAKHVERDIEV K R,GULIEV R I,SALAEV E Y,et al.. Investigation of linear and nonlinear optical properties of GaSxSe1-x crystals[J]. Sov. J. Quantum Electron.,1982,12:947-948. [4] SUHRE D R,SINGH N B,BALAKRISHNA V,et al.. Improved crystal quality and harmonic generation in GaSe doped with indium[J]. Opt. Lett.,1997,22:775-777. [5] SINGH N B,SUHRE D R,ROSCH W,et al.. Modified GaSe crystals for mid-IR applications[J]. J. Cryst. Growth,1999,198:588-592. [6] HSU Y K,CHEN C W,HUANG J Y,et al.. Erbium doped GaSe crystal for mid-IR applications[J]. Opt. Express,2006,14:5484-5491. [7] FENG Z S,KANG Z H,WU F G,et al.. SHG in doped GaSe∶In crystals[J]. Opt. Express,2008,16:9978-9985. [8] ZHANG H Z,KANG Z H,JIANG Y,et al.. SHG phase matching in GaSe and mixed GaSe1-xSx,x≤0.412, crystals at room temperature[J]. Opt. Express,2008,16:9951-9957. [9] RAK Z,MAHANTI S D,MANDAL K C,et al.. Doping dependence of electronic and mechanical properties of GaSe1-xTex and Ga1-xInxSe from first principles[J]. Phys. Rev. B,2010,82:155203. [10] SHI W,DING Y J. A monochromatic and high-power terahertz source tunable in the ranges of 2.7~38.4 and 58.2~3540 μm for variety of potential applications[J]. Appl. Phys. Lett.,2004,84:1635-1637. [11] DING Y J,SHI W. Widely tunable monochromatic THz sources based on phase-matched difference-frequency generation in nonlinear-optical crystals:a novel approach[J]. Laser Phys.,2006,16:562-570. [12] ATUCHIN V V,ANDREEV Y M,SARKISOV S Y,et al.. GaSe1-xSx crystals for terahertz frequency range[C]//10th Annual International Conference and Seminar on Micro/Nanotechnologies and Electron Devices(EDM 2009),July 1-6,2009,Novosibirsk Tomsk,Russia,2009:96-99. [13] ANDREEV Y M,BEREZNAYA S A,VINNIK E M,et al.. Optical properties of GaSe1-xSx in THz range[C]//Eight Siberian Conference on Climate and Ecological Monitoring,Oct 8-10,2009,Tomsk,Russia,2009:375-376.(in Russian) [14] LUO Z W,GU X A,ZHU W C,et al.. Optical properties of GaSe∶S crystals in terahertz frequency range[J]. Opt. Precision Eng.,2011,19:354-359.(in Chinese) [15] ANDREEV Y M,LANSKII G V,ORLOV S N,et al.. Physical properties, phase matching and frequency conversion in GaSe1-xSx, Ga1-xInxSe and GaSe1-xTex[C]//17th Int. Conf. on Advanced Laser Technologies,Sept 26-Oct 1,2009,Antalya,Turkey,2009. [16] SARKISOV S Y,NAZAROV M M,TOLBANOV O P,et al.. Generation and detection of THz pulsed radiation by GaSe GaSe, GaSe1-xTex, GaSe1-xSx, crystals[C]//IX Russian Conf. on Semiconductor Physics,Sept 28-Oct 3,2009,Novosibirsk Tomsk,Russia,2009.(in Russian) [17] ZHANG L M,GUO J,LI D J,et al.. Dispersion properties of GaSe1-xSx in the terahertz range[J]. J. Appl. Spectr.,2011,77:850-856. [18] MANDAL K C,KANG S H,CHOI M,et al.. III VI chalcogenide semiconductor crystals for broadband tunable THz sources and sensors[J]. IEEE J. Sel. Top. in Quant. Electron.,2008,14:284-288. [19] CHEN C W,HSU Y K,HUANG J Y,et al.. Generation properties of coherent infrared radiation in the optical absorption region of GaSe crystal[J]. Opt. Express,2006,14:10636-10644. [20] CHEN C W,TANG T T,LIN S H,et al.. Optical properties and potential applications of ε-GaSe at terahertz frequencies[J]. J. Opt. Soc. Am. B,2009,26:A58-A65. [21] ZHANG Y F,WANG R,KANG Z H,et al.. AgGaS2 and Al doped GaSe for IR application[J]. Opt. Commun.,2011,284:1677 1681. [22] ANDREEV Y M,VINNIK E M,LANSKII G V,et al.. Generation of tunable THz emission in solid solution GaSe1-xTex crystals[C]//Eight Siberian Conference on Climate and Ecological Monitoring,Oct 8-10,2009,Tomsk,Russia,2009:380-381.(in Russian) [23] ANDREEV Y M,VINNIK E M,LANSKII G V. Layered compound semiconductor GaSe and GaTe crystals for THz applications[J]. Mater. Res. Soc. Symp. Proc.,2007,969:W03-W15. [24] LUO C W,KU S A,CHU W C,et al.. Physical property of the crystals grown from GaSe∶AgGaSe2melt and application in Mid-IR facilities[C]//Int. Conference, Atomic and Molecular Pulsed,Sept 12-16,2011,Tomsk,Russia,2011:117. [25] SARKISOV S Y,NAZAROV M M,SHKURINOV A P,et al.. GaSe1-xSx and GaSe1-xTex solid solutions for terahertz generation and detection[C]//34th Int. Conf. on Infrared,Millimeter and Terahertz wave(IRMMW-THz-2009),Sept 21-25,2009,Busan,South Korea,2009. [26] DAS S,GHOSH C,VOEVODINA O G,et al.. Modified GaSe crystal as a parametric frequency converter[J]. Appl. Phys. B,2006,82:43-46. [27] ANDREEV Y M,ATUCHIN V V,LANSKII G V,et al.. Growth,real structure and applications of GaSe1-xSx crystals[J]. Mat. Sci. Eng. B,2006,128:205-210. [28] WANG T J,GAO J C,ANDREEV Y M,et al.. GaSe1-xSx solid solutions[J]. Rus. Phys. J.,2007,50:560-565. [29] QU Y,KABF Z H,WANG T J,et al.. GaSe1-xSx second harmonic generators for CO2 lidars[J]. Atmos. Oceanic Opt.,2008,21:146-151. [30] KU S A,LUO C W,LIO H L,et al.. Optical properties of nonlinear solid solution GaSe1-xSx(0<x≤0.4) crystals[J]. Rus. Phys. J.,2008,51:1083-1089. [31] MAYER G V,KOPYLOVA T N,ANDREEV Y M,et al.. Parametrical conversion of the frequency of organic lasers into the middle-IR range of the spectrum[J]. Rus. Phys. J.,2009,52:640-645. [32] CHU L L,ZHANG I F,KANG Z H,et al.. Phase matching for the second harmonic generation in GaSe crystals[J]. Rus. Phys. J.,2011,53:1235-1242. [33] ANDREEV Y M,KOKH K A,LANSKII G V V,et al.. Structural characterization of pure and doped GaSe by nonlinear optical method[J]. J. Cryst. Growth,2011,318:1164-1166. [34] HAYEK M,BRAFMAN O,LIETH R M A. Splitting and coupling of lattice modes in the layer compounds GaSe, GaS, and GaSexS1-x[J]. Phys. Rev. B,1973,8:2772-2779. [35] VTODIEV I,LEONTIE L,CARAMAN M,et al.. Optical properties of p-GaSe single crystals doped with Te[J]. J. App. Phys.,2009,105:023524. [36] YOSHIDA H,NAKASHIMA S,MITSUISHI A. Phonon Raman spectra of layer compound GaSe[J]. Phys. Stat. Sol.(b),1973,59:655-666. [37] MAMEDOV G M,KARABULUT M,ERTAP H,et al.. Exciton photoluminescence, photoconductivity and absorption in GaSe0.9Te0.1 alloy crystals[J]. J. Lumines.,2009,129:226-230. [38] ABDULLAEV G B,ALLAKHVERDIEV K R,BABAEV S S,et al.. Raman scattering from GaSe1-xTex[J]. Solid State Commun.,1980,34:125-128. [39] SHIGETOMI S,IKARI T. Optical and electrical characteristics of p-GaSe doped with Te[J]. J. Appl. Phys.,2004,95:6480-6482. [40] MENESES E A,JANNUZZI N,FREITAS J R,et al.. Photoluminescence of layered GaSe1-xTex crystals[J]. Phys. Stat. Sol.(b),1976,78:K35-K38.
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