氮掺杂碳纳米点的研究进展

李迪; 孟李; 曲松楠

doi:10.37188/CO.2020-0035

Volume 13 Issue 5

Sep. 2020

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Chinese Optics > 2020 > 13(5): 899-918.

LI Di, MENG Li, QU Song-nan. Research progress on nitrogen-doped carbon nanodots[J]. Chinese Optics, 2020, 13(5): 899-918. doi: 10.37188/CO.2020-0035

Citation:

LI Di, MENG Li, QU Song-nan. Research progress on nitrogen-doped carbon nanodots[J]. Chinese Optics, 2020, 13(5): 899-918. doi: 10.37188/CO.2020-0035

LI Di, MENG Li, QU Song-nan. Research progress on nitrogen-doped carbon nanodots[J]. Chinese Optics, 2020, 13(5): 899-918. doi: 10.37188/CO.2020-0035

Citation:

LI Di, MENG Li, QU Song-nan. Research progress on nitrogen-doped carbon nanodots[J]. Chinese Optics, 2020, 13(5): 899-918. doi: 10.37188/CO.2020-0035

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Research progress on nitrogen-doped carbon nanodots

doi: 10.37188/CO.2020-0035

LI Di^{1
,
,},
MENG Li^{1, 2
,},
QU Song-nan^{3
,
,}

1.
State Key Laboratory of Luminescence and Applications, Changchun Institute of Optics, Fine Mechanics and Physics, Chinese Academy of Sciences, Changchun 130033, China
2.
University of Chinese Academy of Sciences, Beijing 100049, China
3.
Joint Key Laboratory of the Ministry of Education, Institute of Applied Physics and Materials Engineering, University of Macau, Taipa, Macau 999078, China

Funds: Supported by National Natural Science Foundation of China (No.61975200); Jilin Province Science and Technology Research Projects (No. 20170101191JC, No. 20180101190JC, No. 20170101042JC); the Youth Innovation Promotion Association of CAS (No. 2018252); NSFC's Excellent Young Scientists Fund (HK & Macau) (No. 61922091); Funded by University of Macau (No. SRG2019-00163-IAPME)

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Corresponding author: lidi15@ciomp.ac.cn; songnanqu@um.edu.mo
Received Date: 06 Mar 2020
Rev Recd Date: 08 Apr 2020

Available Online: 10 Sep 2020

Publish Date: 01 Oct 2020

Abstract

Abstract

In recent years, carbon nanodot (CDs) have been widely researched due to their unique luminescent properties, good biocompatibility, low toxicity and high photostability. These characteristics invite potential applications in optoelectronic devices, visible light communication, tumor therapy, biological imaging and other fields. There are a variety of CDs according to the different starting materials and synthesis routes. In this paper, we will systematically review nitrogen-doped CDs synthesized from citric acid and urea as the main precursor materials in our group in recent years, discuss their physicochemical properties, explore the methods and principles of CDs energy band regulation, and introduce the application progress of CDs.
- carbon nanodots,
- nitrogen doping,
- photoluminescent materials

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References(58)

References

XU X Y, RAY R, GU Y L, et al. Electrophoretic analysis and purification of fluorescent single-walled carbon nanotube fragments[J]. Journal of the American Chemical Society, 2004, 126(40): 12736-12737. doi: 10.1021/ja040082h

MEHTA A, MISHRA A, BASU S, et al. Band gap tuning and surface modification of carbon dots for sustainable environmental remediation and photocatalytic hydrogen production-A review[J]. Journal of Environmental Management, 2019, 250: 109486. doi: 10.1016/j.jenvman.2019.109486

康倩文, 张国, 柴瑞涛, 等. 基于碳纳米点荧光增强检测铝离子[J]. 分析化学,2019,47(12):1901-1908.

KANG Q W, ZHANG G, CHAI R T, et al. Synthesis of carbon nanodots for detection of aluminum ion with fluorescence enhancement[J]. Chinese Journal of Analytical Chemistry, 2019, 47(12): 1901-1908. (in Chinese)

XU X W, ZHANG K, ZHAO L, et al. Aspirin-based carbon dots, a good biocompatibility of material applied for bioimaging and anti-inflammation[J]. ACS Applied Materials &Interfaces, 2016, 8(48): 32706-32716.

钟青梅, 黄欣虹, 覃庆敏, 等. 以碳量子点为过氧化物模拟酶的葡萄糖测定方法[J]. 分析化学,2018,46(7):1062-1068. doi: 10.11895/j.issn.0253-3820.171396

ZHONG Q M, HUANG X H, QIN Q M, et al. Determination of glucose based on carbon quantum dots as peroxidase mimetic enzyme[J]. Chinese Journal of Analytical Chemistry, 2018, 46(7): 1062-1068. (in Chinese) doi: 10.11895/j.issn.0253-3820.171396

CHEN A Y, LIANG W B, WANG H J, et al. Anodic electrochemiluminescence of carbon dots promoted by nitrogen doping and application to rapid cancer cell detection[J]. Analytical Chemistry, 2020, 92(1): 1379-1385. doi: 10.1021/acs.analchem.9b04537

邓帅, 李雨珊, 段延芳, 等. 荧光碳点在脊椎类模式动物斑马鱼中的活体成像与毒理学研究[J]. 发光学报,2015,36(4):485-490. doi: 10.3788/fgxb20153604.0485

DENG SH, LI Y SH, DUAN Y F, et al. Flourescent imaging and toxicology study of carbon dots in transparent zebrafishes[J]. Chinese Journal of Luminescence, 2015, 36(4): 485-490. (in Chinese) doi: 10.3788/fgxb20153604.0485

XIONG Y, SCHNEIDER J, RECKMEIER C J, et al. Carbonization conditions influence the emission characteristics and the stability against photobleaching of nitrogen doped carbon dots[J]. Nanoscale, 2017, 9(32): 11730-11738. doi: 10.1039/C7NR03648E

YUAN F L, LI SH H, FAN Z T, et al. Shining carbon dots: synthesis and biomedical and optoelectronic applications[J]. Nano Today, 2016, 11(5): 565-586. doi: 10.1016/j.nantod.2016.08.006

ZHOU ZH J, TIAN P F, LIU X Y, et al. Hydrogen peroxide-treated carbon dot phosphor with a bathochromic-shifted, aggregation-enhanced emission for light-emitting devices and visible light communication[J]. Advanced Science, 2018, 5(8): 1800369. doi: 10.1002/advs.201800369

ARDEKANI S M, DEHGHANI A, HASSAN M, et al. Two-photon excitation triggers combined chemo-photothermal therapy via doped carbon nanohybrid dots for effective breast cancer treatment[J]. Chemical Engineering Journal, 2017, 330: 651-662. doi: 10.1016/j.cej.2017.07.165

SHI Y P, PAN Y, ZHONG J, et al. Facile synthesis of gadolinium (III) chelates functionalized carbon quantum dots for fluorescence and magnetic resonance dual-modal bioimaging[J]. Carbon, 2015, 93: 742-750. doi: 10.1016/j.carbon.2015.05.100

姜杰, 李士浩, 严一楠, 等. 氮掺杂高量子产率荧光碳点的制备及其体外生物成像研究[J]. 发光学报,2017,38(12):1567-1574. doi: 10.3788/fgxb20173812.1567

JIANG J, LI SH H, YAN Y N, et al. Preparation of N-doped fluorescent carbon dots with high quantum yield for in-vitro bioimaging[J]. Chinese Journal of Luminescence, 2017, 38(12): 1567-1574. (in Chinese) doi: 10.3788/fgxb20173812.1567

YAN X, CUI X, LI L SH. Synthesis of large, stable colloidal graphene quantum dots with tunable size[J]. Journal of the American Chemical Society, 2010, 132(17): 5944-5945. doi: 10.1021/ja1009376

李俊芬, 王冬秀, 李鹏霞, 等. 一步水热法合成荧光碳点检测锰(Ⅶ)[J]. 分析化学,2019,47(5):731-738.

LI J F, WANG D X, LI P X, et al. One-step hydrothermal synthesis of carbon dots for detection of manganese (Ⅶ)[J]. Chinese Journal of Analytical Chemistry, 2019, 47(5): 731-738. (in Chinese)

KANG S H, MHIN S, HAN H, et al. Ultrafast method for selective design of graphene quantum dots with highly efficient blue emission[J]. Scientific Reports, 2016, 6: 38423. doi: 10.1038/srep38423

DONG Y Q, PANG H CH, REN SH Y, et al. Etching single-wall carbon nanotubes into green and yellow single-layer graphene quantum dots[J]. Carbon, 2013, 64: 245-251. doi: 10.1016/j.carbon.2013.07.059

杜方凯, 张慧, 谭学才, 等. 基于氮掺杂石墨烯量子点/硫化镉纳米晶电化学发光传感器检测硫化氢[J]. 分析化学,2020,48(2):240-247.

DU F K, ZHANG H, TAN X C, et al. Detection of hydrogen sulfide based on nitrogen-doped graphene quantum dots/cadmium sulfide nanocrystals electrochemiluminescence sensor[J]. Chinese Journal of Analytical Chemistry, 2020, 48(2): 240-247. (in Chinese)

邹小波, 史永强, 郑悦, 等. 基于荧光共振能量转移的金纳米粒子/碳量子点荧光纳米探针检测精氨酸[J]. 分析化学,2018,46(6):960-968. doi: 10.11895/j.issn.0253-3820.181096

ZOU X B, SHI Y Q, ZHENG Y, et al. Detection of arginine by AuNPs/CQDs nanoprobes based on fluorescence resonance energy transfer effect[J]. Chinese Journal of Analytical Chemistry, 2018, 46(6): 960-968. (in Chinese) doi: 10.11895/j.issn.0253-3820.181096

曲松楠, 孙铭鸿, 田震, 等. 氮掺杂碳点的合成与应用[J]. 发光学报,2019,40(5):557-580. doi: 10.3788/fgxb20194005.0557

QU S N, SUN M H, TIAN ZH, et al. Synthesis and application of nitrogen-doped carbon dots[J]. Chinese Journal of Luminescence, 2019, 40(5): 557-580. (in Chinese) doi: 10.3788/fgxb20194005.0557

ZHU SH J, SONG Y B, ZHAO X H, et al. The photoluminescence mechanism in carbon dots (graphene quantum dots, carbon nanodots, and polymer dots): current state and future perspective[J]. Nano Research, 2015, 8(2): 355-381. doi: 10.1007/s12274-014-0644-3

ZHAI X Y, ZHANG P, LIU CH J, et al. Highly luminescent carbon nanodots by microwave-assisted pyrolysis[J]. Chemical Communications, 2012, 48(64): 7955-7957. doi: 10.1039/c2cc33869f

LI D, HAN D, QU S N, et al. Supra-(carbon nanodots) with a strong visible to near-infrared absorption band and efficient photothermal conversion[J]. Light:Science &Applications, 2016, 5(7): e16120.

QU S N, SHEN D ZH, LIU X Y, et al. Highly luminescent carbon-nanoparticle-based materials: factors influencing photoluminescence quantum yield[J]. Particle &Particle Systems Characterization, 2014, 31(11): 1175-1182.

QU S N, WANG X Y, LU Q P, et al. A biocompatible fluorescent ink based on water-soluble luminescent carbon nanodots[J]. Angewandte Chemie International Edition, 2012, 51(49): 12215-12218. doi: 10.1002/anie.201206791

QU S N, LIU X Y, GUO X Y, et al. Amplified spontaneous green emission and lasing emission from carbon nanoparticles[J]. Advanced Functional Materials, 2014, 24(18): 2689-2695. doi: 10.1002/adfm.201303352

SK M A, ANANTHANARAYANAN A, HUANG L, et al. Revealing the tunable photoluminescence properties of graphene quantum dots[J]. Journal of Materials Chemistry C, 2014, 2(34): 6954-6960. doi: 10.1039/C4TC01191K

QU S N, ZHOU D, LI D, et al. Toward efficient orange emissive carbon nanodots through conjugated sp²-domain controlling and surface charges engineering[J]. Advanced Materials, 2016, 28(18): 3516-3521. doi: 10.1002/adma.201504891

BAO X, YUAN Y, CHEN J Q, et al. In vivo theranostics with near-infrared-emitting carbon dots—highly efficient photothermal therapy based on passive targeting after intravenous administration[J]. Light:Science &Applications, 2018, 7(1): 91.

LI D, JING P T, SUN L H, et al. Near-infrared excitation/emission and multiphoton-induced fluorescence of carbon dots[J]. Advanced Materials, 2018, 30(13): 1705913. doi: 10.1002/adma.201705913

ZHU X J, SU Q Q, FENG W, et al. Anti-Stokes shift luminescent materials for bio-applications[J]. Chemical Society Reviews, 2017, 46(4): 1025-1039. doi: 10.1039/C6CS00415F

CHEN G Y, QIU H L, PRASAD P N, et al. Upconversion nanoparticles: design, nanochemistry, and applications in theranostics[J]. Chemical Reviews, 2014, 114(10): 5161-5214. doi: 10.1021/cr400425h

LI D, LIANG CH, USHAKOVA E V, et al. Thermally activated upconversion near-infrared photoluminescence from carbon dots synthesized via microwave assisted exfoliation[J]. Small, 2019, 15(50): 1905050. doi: 10.1002/smll.201905050

CHEN Y H, ZHENG M T, XIAO Y, et al. A self-quenching-resistant carbon-dot powder with tunable solid-state fluorescence and construction of dual-fluorescence morphologies for white light-emission[J]. Advanced Materials, 2016, 28(2): 312-318. doi: 10.1002/adma.201503380

OOYAMA Y, YOSHIKAWA S, WATANABE S, et al. Molecular design of novel non-planar heteropolycyclic fluorophores with bulky substituents: convenient synthesis and solid-state fluorescence characterization[J]. Organic &Biomolecular Chemistry, 2006, 4(18): 3406-3409.

SUN M Y, QU S N, HAO ZH D, et al. Towards efficient solid-state photoluminescence based on carbon-nanodots and starch composites[J]. Nanoscale, 2014, 6(21): 13076-13081. doi: 10.1039/C4NR04034A

ZHAI Y CH, ZHOU D, JING P T, et al. Preparation and application of carbon-nanodot@NaCl composite phosphors with strong green emission[J]. Journal of Colloid and Interface Science, 2017, 497: 165-171. doi: 10.1016/j.jcis.2017.03.007

ZHOU D, ZHAI Y CH, QU S N, et al. Electrostatic assembly guided synthesis of highly luminescent carbon-nanodots@BaSO₄ hybrid phosphors with improved stability[J]. Small, 2017, 13(6): 1602055. doi: 10.1002/smll.201602055

LIU E SH, LI D, ZHOU X J, et al. Highly emissive carbon dots in solid state and their applications in light-emitting devices and visible light communication[J]. ACS Sustainable Chemistry &Engineering, 2019, 7(10): 9301-9308.

ZHOU D, JING P T, WANG Y, et al. Carbon dots produced via space-confined vacuum heating: maintaining efficient luminescence in both dispersed and aggregated states[J]. Nanoscale Horizons, 2019, 4(2): 388-395. doi: 10.1039/C8NH00247A

SCHUBERT E F, KIM J K. Solid-state light sources getting smart[J]. Science, 2015, 308(5726): 1274-1278.

LIM S H, KO Y H, RODRIGUEZ C, et al. Electrically driven, phosphor-free, white light-emitting diodes using gallium nitride-based double concentric truncated pyramid structures[J]. Light:Science &Applications, 2016, 5(2): e16030.

ZHAI Y CH, WANG Y, LI D, et al. Red carbon dots-based phosphors for white light-emitting diodes with color rendering index of 92[J]. Journal of Colloid and Interface Science, 2018, 528: 281-288. doi: 10.1016/j.jcis.2018.05.101

TIAN ZH, TIAN P F, ZHOU X J, et al. Ultraviolet-pumped white light emissive carbon dot based phosphors for light-emitting devices and visible light communication[J]. Nanoscale, 2019, 11(8): 3489-3494. doi: 10.1039/C9NR00224C

ELGALA H, MESLEH R, HAAS H. Indoor optical wireless communication: potential and state-of-the-art[J]. IEEE Communications Magazine, 2011, 49(9): 56-62. doi: 10.1109/MCOM.2011.6011734

CHUN H, CHIANG C J, MONKMAN A, et al. A study of illumination and communication using organic light emitting diodes[J]. Journal of Lightwave Technology, 2013, 31(22): 3511-3517. doi: 10.1109/JLT.2013.2284247

MERUGA J M, CROSS W M, MAY P S, et al. Security printing of covert quick response codes using upconverting nanoparticle inks[J]. Nanotechnology, 2012, 23(39): 395201. doi: 10.1088/0957-4484/23/39/395201

ZHANG X T, LI D, ZHOU D, et al. Dual-encryption based on facilely synthesized supra-(carbon nanodots) with water-induced enhanced luminescence[J]. RSC Advances, 2016, 6(83): 79620-79624. doi: 10.1039/C6RA11076B

XU H, CHEN R F, SUN Q, et al. Recent progress in metal-organic complexes for optoelectronic applications[J]. Chemical Society Reviews, 2014, 43(10): 3259-3302. doi: 10.1039/C3CS60449G

BAO X, USHAKOVA E V, LIU E SH, et al. On-Off switching of the phosphorescence signal in a carbon dot/polyvinyl alcohol composite for multiple data encryption[J]. Nanoscale, 2019, 11(30): 14250-14255. doi: 10.1039/C9NR05123F

HONG G S, ANTARIS A L, DAI H J. Near-infrared fluorophores for biomedical imaging[J]. Nature Biomedical Engineering, 2017, 1(1): 0010. doi: 10.1038/s41551-016-0010

PANSARE V J, HEJAZI S, FAENZA W J, et al. Review of long-wavelength optical and NIR imaging materials: contrast agents, fluorophores, and multifunctional nano carriers[J]. Chemistry of Materials, 2012, 24(5): 812-827. doi: 10.1021/cm2028367

FERNANDES N, RODRIGUES C F, MOREIRA A F, et al. Overview of the application of inorganic nanomaterials in cancer photothermal therapy[J]. Biomaterials Science, 2020, 8(11): 2990-3020. doi: 10.1039/D0BM00222D

XU G Y, BAO X, CHEN J Q, et al. In vivo tumor photoacoustic imaging and photothermal therapy based on supra-(carbon nanodots)[J]. Advanced Healthcare Materials, 2019, 8(2): 1800995. doi: 10.1002/adhm.201800995

ZHANG Q F, UCHAKER E, CANDELARIA S L, et al. Nanomaterials for energy conversion and storage[J]. Chemical Society Reviews, 2013, 42(7): 3127-3171. doi: 10.1039/c3cs00009e

ZHANG X L, YANG H, GUO J L, et al. Nitrogen-doped hollow porous carbon nanospheres coated with MnO₂ nanosheets as excellent sulfur hosts for Li-S batteries[J]. Nanotechnology, 2017, 28(47): 475401. doi: 10.1088/1361-6528/aa8f78

WANG R H, XU CH H, SUN J, et al. Three-dimensional Fe₂O₃ nanocubes/nitrogen-doped graphene aerogels: nucleation mechanism and lithium storage properties[J]. Scientific Reports, 2014, 4: 7171.

ZHANG X T, ZHANG ZH Y, HU F, et al. Carbon-dots-derived 3D highly nitrogen-doped porous carbon framework for high-performance lithium ion storage[J]. ACS Sustainable Chemistry &Engineering, 2019, 7(11): 9848-9856.

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