基于喷涂法制备氧化锡薄膜的钙钛矿太阳能电池

王熹; 赵志国; 秦校军; 熊继光; 董超; 白阳; 李煜璟; 陈棋

doi:10.3788/CO.20191205.1040

Volume 12 Issue 5

Oct. 2019

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Chinese Optics > 2019 > 12(5): 1040-1047.

WANG Xi, ZHAO Zhi-guo, QIN Xiao-jun, XIONG Ji-guang, DONG Chao, BAI Yang, LI Yu-jing, CHEN Qi. Perovskite solar cells based on a spray-coating tin oxide film[J]. Chinese Optics, 2019, 12(5): 1040-1047. doi: 10.3788/CO.20191205.1040

Citation:

WANG Xi, ZHAO Zhi-guo, QIN Xiao-jun, XIONG Ji-guang, DONG Chao, BAI Yang, LI Yu-jing, CHEN Qi. Perovskite solar cells based on a spray-coating tin oxide film[J]. Chinese Optics, 2019, 12(5): 1040-1047. doi: 10.3788/CO.20191205.1040

Citation:

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Perovskite solar cells based on a spray-coating tin oxide film

doi: 10.3788/CO.20191205.1040

WANG Xi^{1, 2
,},
ZHAO Zhi-guo^{1
,
,},
QIN Xiao-jun¹,
XIONG Ji-guang¹,
DONG Chao¹,
BAI Yang²,
LI Yu-jing²,
CHEN Qi^{2
,
,}

1.
Huaneng Group Clean Energy Technology Research Institute Co., Led., Beijing 102209, China
2.
School of Material Science and Engineering, Beijing Institute of Technology, Beijing 100081, China

Funds:

National Natural Science Foundation of China 51673025

More Information

Corresponding author: ZHAO Zhi-guo, E-mail: zg_zhao@qny.chng.com.cn; CHEN Qi, E-mail:qic@bit.edu.cn
Received Date: 07 Mar 2019
Rev Recd Date: 03 Apr 2019
Publish Date: 01 Oct 2019

Abstract

Abstract

The electron transport layer(ETL) plays a crucial role in carrier extraction and transportation in perovskite solar cells. Tin(Ⅳ) oxide is widely used as ETL-material in planar perovskite solar cells due to its excellent properties. However, current processes for tin oxide film preparation can hardly meet industrial requirements, such as large-scale and automatic fabrication. Therefore, developing a new fabrication method suitable for industrialization is in urgent demanded. To solve this problem, a high-quality tin oxide film was successfully created using the spray coating method. Experimental results show that the performance of the perovskite solar cells is highly dependent on the thickness of the spray-coated tin oxide film. By optimizing film thickness, power conversion efficiency(PCE) can be improved to 15.72%. The film exhibits a coffee ring phenomenon, which increases the series resistance and limits the PCE. That can be solved by further decreasing the size of the droplets. This paper demonstrates a new method for the fabrication of high-quality, highly adaptable tin oxide films for the industrialization of perovskite solar cells.
- perovskite solar cells,
- electron transport layer,
- tin oxide,
- spraying-coating method

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References(27)

References

[1]	KOJIMA A, TESHIMA K, SHIRAI Y, et al.. Organometal halide perovskites as visible-light sensitizers for photovoltaic cells[J]. Journal of the American Chemical Society, 2009, 131(17):6050-6051. doi: 10.1021/ja809598r
[2]	ZHOU H P, CHEN Q, LI G, et al.. Interface engineering of highly efficient perovskite solar cells[J]. Science, 2014, 345(6196):542-546. doi: 10.1126/science.1254050
[3]	YANG W S, NOH J H, JEON N J, et al.. High-performance photovoltaic perovskite layers fabricated through intramolecular exchange[J]. Science, 2015, 348(6240):1234-1237. doi: 10.1126/science.aaa9272
[4]	BI D Q, YI C Y, LUO J SH, et al.. Polymer-templated nucleation and crystal growth of perovskite films for solar cells with efficiency greater than 21%[J]. Nature Energy, 2016, 1(10):16142. doi: 10.1038/nenergy.2016.142
[5]	National Renewable Energy Laboratory. Best research-cell efficiency[EB/OL]. https://www.nrel.gov/pv/assets/images/efficiency-chart.png.
[6]	LEIJTENS T, EPERON G E, PATHAK S, et al.. Overcoming ultraviolet light instability of sensitized TiO₂ with meso-superstructured organometal tri-halide perovskite solar cells[J]. Nature Communications, 2013, 4:2885. doi: 10.1038/ncomms3885
[7]	JIANG Q, ZHANG X W, YOU J B. SnO₂:a wonderful electron transport layer for perovskite solar cells[J]. Small, 2018, 14(31):1801154. doi: 10.1002/smll.201801154
[8]	JIANG Q, CHU Z M, WANG P Y, et al.. Planar-structure perovskite solar cells with efficiency beyond 21%[J]. Advanced Materials, 2017, 29(46):1703852. doi: 10.1002/adma.201703852
[9]	BAENA J P C, STEIER L, TRESS W, et al.. Highly efficient planar perovskite solar cells through band alignment engineering[J]. Energy & Environmental Science, 2015, 8(10):2928-2934. http://d.old.wanfangdata.com.cn/NSTLQK/NSTL_QKJJ0235545163/
[10]	ANARAKI E H, KERMANPUR A, STEIER L, et al.. Highly efficient and stable planar perovskite solar cells by solution-processed tin oxide[J]. Energy & Environmental Science, 2016, 9(10):3128-3134. http://cn.bing.com/academic/profile?id=324103d1934e557bbf32b0424bc07363&encoded=0&v=paper_preview&mkt=zh-cn
[11]	YANG G, LEI H W, TAO H, et al.. Reducing hysteresis and enhancing performance of perovskite solar cells using low-temperature processed Y-doped SnO₂ nanosheets as electron selective layers[J]. Small, 2017, 13(2):1601769. doi: 10.1002/smll.201601769
[12]	LIU X, TSAI K W, ZHU Z L, et al.. A low-temperature, solution processable tin oxide electron-transporting layer prepared by the dual-fuel combusion method for efficient perovskite solar cells[J]. Advanced Materials Interfaces, 2016, 3(13):1600122. doi: 10.1002/admi.201600122
[13]	CHEN J Y, CHUEH C C, ZHU Z L, et al.. Low-temperature electrodeposited crystalline SnO₂ as an efficient electron-transporting layer for conventional perovskite solar cells[J]. Solar Energy Materials and Solar Cells, 2017, 164:47-55. doi: 10.1016/j.solmat.2017.02.008
[14]	胡明江, 晋兵营.基于CuO/ZnO异质结纳米花的薄膜型丙酮传感器研究[J].分析化学, 2019, 47(3):363-370. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=fxhx201903005 HU M J, JIN B Y. Research on film type acetone sensor based on copper oxide/zinc oxide heterostructure nanoflower[J]. Chinese Journal of Analytical Chemistry, 2019, 47(3):363-370.(in Chinese) http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=fxhx201903005
[15]	王艺, 姜晓, 谭峰, 等.新型氧化铈/氧化锆-梯度扩散薄膜技术用于水体和沉积物中无机砷的形态分析[J].分析化学, 2018, 46(11):1829-1835. doi: 10.11895/j.issn.0253-3820.181395 WANG Y, JIANG X, TAN F, et al.. CeO₂/ZrO₂-based diffusive gradients in thin films technique for measurement of As(Ⅲ) and As(Ⅴ) in water and sediment[J]. Chinese Journal of Analytical Chemistry, 2018, 46(11):1829-1835.(in Chinese) doi: 10.11895/j.issn.0253-3820.181395
[16]	黄芳龙, 陈旦初.金属氧化物薄膜的超声雾化喷涂[J].太阳能学报, 1989, 10(4):418-420. http://www.cnki.com.cn/Article/CJFDTotal-TYLX198904014.htm HUANG F L, CHEN D CH. Ultrasonic atomization spraying of metal oxide film[J]. Acta Energiae Solaris Sinica, 1989, 10(4):418-420.(in Chinese) http://www.cnki.com.cn/Article/CJFDTotal-TYLX198904014.htm
[17]	贾莉, 吕喆, 黄喜强, 等.用于燃料电池的氧化锆薄膜制备方法进展[J].电源技术, 2004, 28(7):449-451. doi: 10.3969/j.issn.1002-087X.2004.07.016 JIA L, LÜ ZH, HUANG X Q, et al.. Progress on manufacturing of zirconia film for fuel cells[J]. Chinese Journal of Power Sources, 2004, 28(7):449-451.(in Chinese) doi: 10.3969/j.issn.1002-087X.2004.07.016
[18]	KRUNKS M, MELLIKOV E. Zinc oxide thin films by the spray pyrolysis method[J]. Thin Solid Films, 1995, 270(1-2):33-36. doi: 10.1016/0040-6090(95)06893-7
[19]	SHINDE V R MAHADIK S B, GUJAR T P, et al.. Supercapacitive cobalt oxide (Co₃O₄) thin films by spray pyrolysis[J]. Applied Surface Science, 2006, 252(20):487-7492. https://www.sciencedirect.com/science/article/pii/S0169433205012602
[20]	PEREDNIS D, GAUCKLER L J. Thin film deposition using spray pyrolysis[J]. Journal of Electroceramics, 2005, 14(2):103-111. doi: 10.1007/s10832-005-0870-x
[21]	SHAMALA K S, MURTHY L C S, RAO K N. Studies on tin oxide films prepared by electron beam evaporation and spray pyrolysis methods[J]. Bulletin of Materials Science, 2004, 27(3):295-301. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=b62d9607fcfac572799a0964339740cc
[22]	CHEN B, YANG M J, PRIYA S, et al.. Origin of J-V hysteresis in perovskite solar cells[J]. The Journal of Physical Chemistry Letters, 2016, 7(5):905-917. doi: 10.1021/acs.jpclett.6b00215
[23]	TU B, SHAO Y F, CHEN W, et al.. Novel molecular doping mechanism for n-doping of SnO₂ via triphenylphosphine oxide and its effect on perovskite solar cells[J]. Advanced Materials, 2019, 31(15):1805944. doi: 10.1002/adma.201805944
[24]	GUILLÉN E, RAMOS F J, ANTA J A, et al.. Elucidating transport-recombination mechanisms in perovskite solar cells by small-perturbation techniques[J]. The Journal of Physical Chemistry C, 2014, 118(40):22913-22922. doi: 10.1021/jp5069076
[25]	孙加振, 邝旻翾, 宋延林.喷墨打印中"咖啡环"效应的调控及应用[J].化学进展, 2015, 27(8):979-985. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=hxjz201508001 SUN J ZH, KUANG M X, SONG Y L. Control and application of "coffee ring" effect in inkjet printing[J]. Progress in Chemistry, 2015, 27(8):979-985.(in Chinese) http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=hxjz201508001
[26]	SEARS W M, GEE M A. Mechanics of film formation during the spray pyrolysis of tin oxide[J]. Thin Solid Films, 1988, 165(1):265-277. doi: 10.1016/0040-6090(88)90698-0
[27]	张培旭, 金永日, 崔俐, 等.基于超声喷泉的超声雾化结合固相萃取法提取西洋参叶中8种人参皂苷[J].分析化学, 2018, 46(4):594-600. http://d.old.wanfangdata.com.cn/Periodical/fxhx201804019 ZHANG P X, JIN Y R, CUI L, et al.. Extraction of eight ginsenosides from leaves of Panax quinquefolium L. by ultrasoinc fountain-based ultrasonic-assisted nebulization extraction coupled with solid phase extraction[J]. Chinese Journal of Analytical Chemistry, 2018, 46(4):594-600.(in Chinese) http://d.old.wanfangdata.com.cn/Periodical/fxhx201804019

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