有机自组装低维圆偏振发光材料的研究进展

王梦竹; 邓勇靖; 刘淑娟; 赵强

doi:10.37188/CO.2020-0192

有机自组装低维圆偏振发光材料的研究进展

doi: 10.37188/CO.2020-0192

1.
南京邮电大学信息材料与纳米技术研究院，江苏南京 210023
2.
有机电子与信息显示国家重点实验室培育基地，江苏南京 210023

基金项目: 国家杰出青年科学基金（No. 61825503）；国家自然科学基金（No. 61775101, No. 61805122）

详细信息

作者简介:
王梦竹（1990—），男，河南信阳人，博士研究生，2019年于温州大学获得硕士学位，主要从事有机圆偏振发光材料的研究。E-mail：18257753336@163.com

赵　强（1978—），男，山东淄博人，教授，2007年于复旦大学获得博士学位，2010年8月晋升为南京邮电大学教授，主要从事有机与生物光电子学研究。E-mail：iamqzhao@njupt.edu.cn

中图分类号: O6-1; O439
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出版历程
- 收稿日期: 2020-10-23
- 修回日期: 2020-11-30
- 网络出版日期: 2021-01-14
- 刊出日期: 2021-01-25

Research progress on organic self-assembling low-dimensional circularly polarized luminescent materials

1.
Institute of Information Materials and Nanotechnology, Nanjing University of Posts and Telecommunications (NUPT), Nanjing 210023, China
2.
Key Laboratory for Organic Electronics and Information Displays and Institute of Advanced Materials (IAM), Nanjing 210023, China

Funds: Supported by National Funds for Distinguished Young Scientists (No. 61825503); National Natural Science Foundation of China (No. 61775101, No. 61805122)

More Information

Corresponding author: iamqzhao@njupt.edu.cn

摘要

摘要: 具有圆偏振发光（CPL）性质的材料由于在3D显示、光学存储以及光学防伪等领域的重要应用，近年来越来越受到研究人员的关注。超分子策略能够将不同类型的分子组装成具有独特功能的低维（零维、一维和二维等）结构，因而成为构筑CPL活性有机低维材料的最有效方法之一。本文从超分子自组装驱动力的角度综述了近几年自组装CPL活性有机低维材料的研究进展。首先，本文系统地总结了现阶段设计自组装CPL活性有机低维材料的策略，其次重点讨论了这类材料的性能及应用，最后探讨了这一领域未来的发展机遇和挑战。
- 圆偏振发光 /
- 有机自组装低维材料 /
- 氢键 /
- 静电作用 /
- 金属配位作用 /
- 主客体相互作用
Abstract: In recent years, materials with Circularly Polarized Luminescence (CPL) have received growing attention due to their wide applications in 3D displays, optical storage, optical security, etc. Supramolecular self-assembling is one of the most effective methods to construct CPL active materials, which can assemble different types of molecules into low-dimensional (0D, 1D and 2D) structures with unique functions. This review summarizes the research progress of self-assembled CPL active organic low-dimensional materials from recent years with emphasis on the driving force of supramolecular self-assembly. Firstly, the review systematically summarizes the current design strategies of self-assembled CPL active organic low-dimensional materials. Secondly, it focuses on their performance and applications. Finally, it discusses the future opportunities and challenges of this rapidly developing field.
- circularly polarized luminescence /
- organic self-assembly low-dimensional materials /
- hydrogen bonding /
- electrostatic interactions /
- metal coordination interactions /
- host-guest interactions

HTML全文

图 1 多重氢键参与的共组装过程。（a）B-DNA结构中的多重氢键。（b）羧酸和吡啶类粘合剂之间的双重氢键能够形成手性纳米结构。（c）芳香族氨基酸和粘合剂的化学结构^[25]

Figure 1. The co-assembly process with multiple hydrogen bonds. (a) Multiple hydrogen bonds in B-DNA structures. (b) The double hydrogen bond between carboxylic acids and pyridine-based binders can form chiral nanostructures. (c) The chemical structures of aromatic amino acids and binders^[25]

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图 2 π-结构单元（GluCN）分别与硫黄素T（ThT）和羧酸氰基二苯乙烯衍生物（CAN）共组装示意图^[30]

Figure 2. Illustration of the co-assembly of the π-structural unit (GluCN), thioflavin T (ThT) and carboxylic cyanostilbene derivative (CAN), respectively^[30]

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图 3 手性稀土四面体笼的圆偏振发光和手性记忆效应^[35]

Figure 3. Circularly polarized luminescence and chiral memory effect of chiral rare earth tetrahedral cage^[35]

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图 4 手性MOF的CPL示意图^[41]

Figure 4. Schematic illustration of CPL with chiral MOF^[41]

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图 5 Cu₁₄纳米团簇的合成及其手性特征^[45]

Figure 5. Synthesis and chirality of Cu₁₄ nanoclusters^[45]

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图 6 钙钛矿纳米晶体手性示意图^[48]

Figure 6. Illustration of the origin of chirality in perovskite nanocrystals^[48]

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图 7 可能的自组装路线示意图^[57]

Figure 7. Illustration of a possible self-assembly route^[57]

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图 8 （a）对映体(S)-BPPOACZ和(R)-BPPOACZ的化学结构。（b）(R)-BPPOACZ的单晶结构。（c）(R)-BPPOACZ的HOMO和LUMO轨道分布示意图^[61]。

Figure 8. (a) Chemical structures of the enantiomers (S)-BPPOACZ and (R)-BPPOACZ. (b) Single crystal structure of (R)-BPPOACZ. (c) HOMO and LUMO orbital distributions of (R)-BPPOACZ^[61].

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