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非线性光限幅材料原理、性能表征及研究进展

吕泽 方佑 冯迢 宗楠 李云飞 张申金 谢政 彭钦军

吕泽, 方佑, 冯迢, 宗楠, 李云飞, 张申金, 谢政, 彭钦军. 非线性光限幅材料原理、性能表征及研究进展[J]. 中国光学(中英文), 2022, 15(4): 625-639. doi: 10.37188/CO.2021-0195
引用本文: 吕泽, 方佑, 冯迢, 宗楠, 李云飞, 张申金, 谢政, 彭钦军. 非线性光限幅材料原理、性能表征及研究进展[J]. 中国光学(中英文), 2022, 15(4): 625-639. doi: 10.37188/CO.2021-0195
LV Ze, FANG You, FENG Tiao, ZONG Nan, LI Yun-fei, ZHANG Shen-jin, XIE Zheng, PENG Qin-jun. The principle, performance characterization and research progress of nonlinear optical limiting materials[J]. Chinese Optics, 2022, 15(4): 625-639. doi: 10.37188/CO.2021-0195
Citation: LV Ze, FANG You, FENG Tiao, ZONG Nan, LI Yun-fei, ZHANG Shen-jin, XIE Zheng, PENG Qin-jun. The principle, performance characterization and research progress of nonlinear optical limiting materials[J]. Chinese Optics, 2022, 15(4): 625-639. doi: 10.37188/CO.2021-0195

非线性光限幅材料原理、性能表征及研究进展

doi: 10.37188/CO.2021-0195
基金项目: 国家自然科学基金重大项目(No. 51890864);中科院理化所所长基金(No. E0A8053H12)
详细信息
    作者简介:

    吕 泽(1997—),女,山西运城人,博士研究生,2019年于北京化工大学获得学士学位,主要从事中红外全固态激光器方面的研究。E-mail:lvze191@mails.ucas.ac.cn

    宗 楠(1982—),女,辽宁阜新人,博士,副研究员,2010年于中科院物理研究所获得博士学位,主要从事新型全固态激光及非线性频率变换技术研究。E-mail:zongnan@mail.ipc.ac.cn

    李云飞(1993—),男,山西晋城人,博士,博士后,2020年于中国科学院理化技术研究所获得博士学位,主要从事非线性光学材料方向研究。E-mail:liyunfei@mail.ipc.ac.cn

    张申金(1978—),男,山东新泰人,博士,研究员,2007年于西安电子科技大学获得博士学位,主要从事固体激光、非线性光学及大功率激光应用等方面的研究。E-mail:zhangshenjin@163.com

  • 中图分类号: TN244

The principle, performance characterization and research progress of nonlinear optical limiting materials

Funds: Supported by Major Program of National Natural Science Foundation of China (No. 51890864); Fund of Technical Institute of Physics and Chemistiy, Chinese Academy of Sciences (No. E0A8053H12).
More Information
  • 摘要:

    激光防护材料在保护人眼和光学器件免受强激光破坏方面具有重要意义,其中基于非线性光学原理工作的固态光限幅材料有望成为未来激光防护的主体。本文介绍了光限幅材料的研究背景、工作机理、参数指标以及测试技术,综述了目前具有实用前景的多类光限幅材料的研究进展,对无机半导体材料、共轭有机高分子、无机金属团簇、碳纳米材料、二维材料等5类材料做了重点介绍,探讨这些光限幅材料的发展前景,并介绍了相关材料在固态基质中器件化的研究现状。

     

  • 图 1  典型的光限幅效应

    Figure 1.  Typical optical limiting effect

    图 2  反饱和吸收机制[2]

    Figure 2.  Reverse saturated absorption mechanism[2]

    图 3  双光子吸收机制[2]

    Figure 3.  Two-photon absorption mechanism[2]

    图 4  非线性折射原理图[2]。(a)典型的自散焦光学结构;(b)典型的自聚焦光学结构

    Figure 4.  Nonlinear refraction schematic diagrams[2]. (a) Typical self-defocusing optical structure; (b) typical self-focusing optical structure

    图 5  光限幅响应曲线图[4]

    Figure 5.  The response of an optical limiter[4]

    图 6  Z-扫描系统原理图[4]

    Figure 6.  Z-scan system schematic diagram[4]

    图 7  (a)开孔Z-扫描曲线及(b)闭孔Z-扫描曲线

    Figure 7.  (a) Open hole Z-scan curve and (b) close hole Z-scan curve

    表  1  5类光限幅材料的限幅机理、性能特点及目前的技术指标

    Table  1.   The mechanism, characteristics and the technical indicators of the five types of optical limiting materials

    材料类别光限幅机理性能特点代表材料光限幅技术指标参考文献
    无机半导体材料双光子吸收
    载流子吸收
    非线性折射
    制备简单、成本低廉、
    物化性质稳定,限幅波段单一、
    线性吸收大
    CuS限幅阈值:0.88 J/cm2@532 nm[15]
    ZnO限幅阈值:~6 mW@633 nm[16]
    TiS2限幅阈值:0.57 J/cm2[17]
    共轭有机高分子反饱和吸收适用于脉宽纳秒
    量级以上的脉冲激光、
    限幅阈值低
    J-dimers限幅阈值:0.03 J/cm2@532 nm[18]
    (NiNc(COONa)4/TiO2)n限幅波段:600 nm@18 ps[19]
    MnPcCl限幅波段:633 nm,533 nm[20]
    无机金属团簇非线性折射
    反饱和吸收
    结构多样、线性吸收小、
    非线性性能强
    MoS4Cu2限幅阈值:0.35 J/cm2@532 nm[21]
    碳基纳米材料反饱和吸收
    非线性折射
    非线性散射
    限幅阈值低、限幅波段宽,
    损伤阈值高、适用于纳秒、
    皮秒脉冲激光,固态化技术成熟
    C60(Toluene)限幅阈值:0.2 J/cm2@532 nm[22]
    MWNTS限幅阈值:1 J/cm2@532 nm[23]
    GO-Pt-2限幅阈值:0.85 J/cm2@532 nm[24]
    二维材料反饱和吸收
    非线性折射
    非线性散射
    限幅波段宽,
    可用于飞秒脉冲激光,
    物化性质优异
    Si−antimonene限幅波段:532~2000 nm
    限幅阈值:0.3~2 J/cm2@532 nm
    [25]
    F16PcGa-BP限幅波段:415~590 nm
    限幅阈值:2.64 J/cm2@532 nm
    [26]
    下载: 导出CSV
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  • 收稿日期:  2021-11-08
  • 录用日期:  2022-01-24
  • 修回日期:  2021-11-18
  • 网络出版日期:  2022-04-27

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