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正交激发发射上转换纳米材料的设计、制备与应用

贾恒 冯晓锐 李大光 秦伟平 杨龙 何伟艳 马惠言 滕英跃

贾恒, 冯晓锐, 李大光, 秦伟平, 杨龙, 何伟艳, 马惠言, 滕英跃. 正交激发发射上转换纳米材料的设计、制备与应用[J]. 中国光学(中英文). doi: 10.37188/CO.2022-0134
引用本文: 贾恒, 冯晓锐, 李大光, 秦伟平, 杨龙, 何伟艳, 马惠言, 滕英跃. 正交激发发射上转换纳米材料的设计、制备与应用[J]. 中国光学(中英文). doi: 10.37188/CO.2022-0134
JIA Heng, FENG Xiao-rui, LI Da-guang, QIN Wei-ping, YANG Long, HE Wei-yan, MA Hui-yan, TENG Ying-yue. Design, Preparation and Application of Orthogonal Excitation-Emission Upconversion Nanomaterials[J]. Chinese Optics. doi: 10.37188/CO.2022-0134
Citation: JIA Heng, FENG Xiao-rui, LI Da-guang, QIN Wei-ping, YANG Long, HE Wei-yan, MA Hui-yan, TENG Ying-yue. Design, Preparation and Application of Orthogonal Excitation-Emission Upconversion Nanomaterials[J]. Chinese Optics. doi: 10.37188/CO.2022-0134

正交激发发射上转换纳米材料的设计、制备与应用

doi: 10.37188/CO.2022-0134
基金项目: 国家自然科学基金项目: (No. 12174150,No. 11774132,No. 21766023);内蒙古科技计划项目(No. 2019GG268);内蒙古工业大学科学研究项目(No. ZZ202108);内蒙古工业大学科研启动金项目(No. DC2200000916)
详细信息
    作者简介:

    贾 恒(1990—),男,山西阳高人,博士,内蒙古工业大学教师,硕士生导师,2021年于吉林大学获得博士学位,主要从事稀土光电功能材料、上转换发光调控及应用等方面的研究。E-mail:jiaheng17@mails.jlu.edu.cn

    秦伟平(1961—),男,江苏南通人,吉林大学电子科学与工程学院、集成光电子国家重点联合实验室教授,博士生导师,1984年于清华大学工程物理系获得学士学位,1999年于中国科学院长春物理研究所获得博士学位,主要从事先进光子学材料与器件、固体发光学、稀土纳米发光材料、光频上转换发光、红外光光催化、多离子合作量子跃迁、科学创新理论与创新学等方面的研究,2010年荣获吉林省科学技术进步一等奖,2011年荣获国家自然科学奖二等奖,2016年荣获吉林省自然科学奖一等奖,主持并完成各类科研项目30余项,发表SCI论文300余篇,获专利授权40余件,H因子59,2014~2021年连续8年进入Elsevier发布的中国高被引学者榜单。E-mail:wpqin@jlu.edu.cn

    滕英跃(1976—),男,山东掖县人,博士,内蒙古工业大学教授,硕士生导师,1998年于内蒙古工业大学化工学院硅酸盐专业任教,2014-至今任化工学院无机非金属材料工程系主任,长期从事非金属材料、褐煤应用等方面的研究,主持国家及自治区科研项目3项,企业横向合作项目1项,校级优秀教学团队负责人,荣获内蒙古工业大学教学成果一等奖、三等奖各1次,发表文章10余篇,授权发明专利2项。E-mail:tengyingyue@163.com

  • 中图分类号: O433; O614.33

Design, Preparation and Application of Orthogonal Excitation-Emission Upconversion Nanomaterials

Funds: Supported by National Natural Science Foundation of China (No. 12174150, No. 11774132, No.21766023); Plan of Scientific and Technology of Inner Mongolia (No. 2019GG268); Research Project of Inner Mongolia University of Technology (No. ZZ202108); Scientific Research Startup Fund of Inner Mongolia University of Technology (No. DC2200000916)
More Information
  • 摘要:

    稀土掺杂的上转换发光纳米材料在信息安全、生物医学、光纤通信、显示和能源等众多领域有着巨大的应用潜力,受到了相关各领域研究人员的广泛关注。特别是近年来发展起来的具有正交激发发射特性的上转换发光纳米颗粒,其光色输出可在不同的激发条件下产生动态变化,因而产生出一系列新的特性与功能,大大地扩展了应用范围。本文综述稀土离子正交上转换发光的发展历程,系统论述了基于核壳结构的正交激发发射体系的设计原理和构建方法,介绍了其在信息存储、安全防伪、显示、传感、生物成像及治疗等领域的最新研究进展,并探讨了未来相关研究中可能面临的机遇和挑战。

     

  • 图 1  二元正交激发发射体系的结构设计示意图

    Figure 1.  Schematic diagram of structure design for binary orthogonal excitation-emission systems

    图 2  基于正交双色上转换发光的二元正交激发发射体系。(a)具有蓝-绿双色正交发光的四层核壳纳米结构NaGdF4:Yb/Tm@NaGdF4@NaYbF4:Nd@Na(Yb,Gd)F4:Ho@NaGdF4示意图和在980/808 nm二元激发下的发射光谱及对应的发光照片[41];(b) 蓝-绿双色正交发光的NaYF4: Nd/Yb/Tm@NaYF4:Nd@NaYF4@NaYF4:Yb /Er三层核壳结构示意图和在980/808 nm二元激发下的发射光谱及对应的发光照片[33];(c)具有不依赖于激发功率密度的高色纯度蓝-绿双色正交发射的NaGdF4:Yb,Er@NaYF4:Yb@NaGdF4:Yb,Nd@ NaYF4@NaGdF4: Yb,Tm@NaYF4五层核壳结构示意图和在980/796 nm二元激发下的发射光谱及对应的发光照片[48];具有不同中间NaYF4纳米壳层厚度的NaGdF4:Yb,Er@NaYF4@NaYF4:Yb,Tm@NaYbF4:Nd@NaYF4四层核壳结构在808/980 nm二元激发下的发射光谱[49]。(a)转载自文献[41],版权所有(2013)威立出版集团; (b)转载自文献[33],版权所有(2014)威立出版集团; (c)转载自文献[48],版权所有(2016)威立出版集团; (d)转载自文献[49],版权所有(2017)美国化学学会

    Figure 2.  Binary orthogonal excitation-emission systems for orthogonal dual-color upconversion luminescence. (a) Schematic illustration of core/quadruple-shell NaGdF4:Yb/Tm@NaGdF4@NaYbF4:Nd@Na(Yb,Gd)F4:Ho@ NaGdF4 with blue-green dual-color orthogonal luminescence and its corresponding emission spectra and photographs under 980/808 nm binary excitations[41]; (b) Schematic illustration of core/triple-shell NaYF4:Nd/Yb/ Tm@NaYF4:Nd@NaYF4@ NaYF4:Yb/Er with blue-green dual-color orthogonal luminescence and its corresponding emission spectra and photographs under 980/808 nm binary excitations[33]; (c) Schematic illustration of core/quintuple-shell NaGdF4:Yb,Er@NaYF4:Yb@NaGdF4:Yb,Nd@NaYF4@NaGdF4:Yb,Tm@ NaYF4 with excitation power density-independent blue-green high-pure dual-color orthogonal luminescence and its corresponding emission spectra and photographs under 980/796 nm binary excitations[48]; (d) Emission spectra of core/quadruple-shell NaGdF4:Yb,Er@NaYF4@NaYF4:Yb, Tm@NaYbF4:Nd@NaYF4 with varied thickness of an NaYF4 interlayer under 808/980 nm binary excitations[49]. (a) Reproduced with permission ref. [41]. Copyright 2013, Wiley-VCH; (b) Reproduced with permission ref. [33]. Copyright 2014, Wiley-VCH; (c) Reproduced with permission ref. [48]. Copyright 2016, Wiley-VCH; (d) Reproduced with permission ref. [49]. Copyright 2017, American Chemical Society.

    图 3  正交双色发射的二元正交激发发射体系。(a)基于敏化剂Er3+的绿-蓝双色正交发射NaYF4:Er@ NaYF4@NaYF4:Yb/Tm@NaYF4三层核壳纳米结构示意图和在1532/980 nm二元激发下的发射光谱及对应的发光照片[50];(b)基于NaErF4:Tm红光发射核的多层核壳纳米结构示意图和在1550 nm和980/808 nm二元激发下的发光照片[20];(c) 基于Er3+自敏化的蓝-绿双色正交发射NaYF4:Er@NaYF4@NaYF4:Yb/Tm双层核壳纳米结构示意图和在808/940 nm二元激发下的发射光谱[51];(d) 基于NaErF4红光发射核的红-蓝双色正交发射NaErF4@NaYF4@NaYbF4:Tm@NaYF4三层核壳纳米结构示意图和在800/980 nm二元激发下的发射光谱及对应的发光照片[52];(e)基于单发光层的红-绿双色正交发射NaErF4:Yb/Tm@NaYF4:Yb@ NaNdF4:Yb双层核壳纳米结构示意图和在980/808 nm二元激发下的发射光谱及对应的发光照片[55];(f) 基于单发光层的二元正交激发发射体系(NaYF4:Yb/Er/Mn@ NaYF4:Yb@NaNdF4:Yb)示意图和在980/808 nm二元激发下的发射光谱及对应的发光照片[56]。(a)转载自文献[50],版权所有(2018)威立出版集团; (b)转载自文献[20],版权所有(2019)威立出版集团; (c)转载自文献[51],版权所有(2018)皇家化学学会; (d)转载自文献[52],版权所有(2018)美国化学学会; (e)转载自文献[55],版权所有(2019)自然出版集团; (f)转载自文献[56],版权所有(2020)威立出版集团

    Figure 3.  Binary orthogonal excitation-emission systems with orthogonal dual-color emissions. (a) Schematic illustration of Er3+ sensitizer-based core/triple-shell NaYF4:Er@NaYF4@ NaYF4:Yb/Tm@NaYF4 with green-blue dual-color orthogonal emissions and its corresponding emission spectra and photographs under 1532/980 nm binary excitations[50]; (b)Schematic illustration of red-emitting NaErF4:Tm core-based multilayer core–shell nanostructures and their corresponding photographs under 1550 nm and 980/808 nm binary excitations[20]; (c)Schematic illustration of red-emitting NaErF4 core-based core/triple-shell NaErF4@NaYF4@NaYbF4:Tm @NaYF4 with red-blue dual-color orthogonal emissions and its corresponding emission spectra and photographs under 808/980 nm binary excitations[52]; (d)Schematic illustration of self-sensitization of Er3+-based core/double-shell NaYF4:Er@NaYF4@NaYF4:Yb/Tm with blue-green dual-color orthogonal emissions and its corresponding emission spectra under 940/808 nm binary excitations[51]; (e) Schematic illustration of a single-emissive layer-based core/double-shell NaErF4:Yb/Tm@NaYF4:Yb@NaNdF4:Yb with red-green dual-color orthogonal emissions and its corresponding emission spectra and photographs under 980/808 nm binary excitations[55]; (f) Schematic illustration of a single-emissive layer-based binary orthogonal excitation-emission systems (NaYF4:Yb/Er/Mn@ NaYF4:Yb@NaNdF4:Yb) and its corresponding emission spectra and photographs under 980/808 nm binary excitations[56]. (a) Reproduced with permission ref. [50]. Copyright 2018, Wiley-VCH; (b) Reproduced with permission ref. [20]. Copyright 2019, Wiley-VCH; (c) Reproduced with permission ref. [51]. Copyright 2018, Royal Society of Chemistry; (d) Reproduced with permission ref. [52]. Copyright 2018, American Chemical Society; (e) Reproduced with permission ref. [55]. Copyright 2019, Nature Publishing Group; (f) Reproduced with permission ref. [56]. Copyright 2020, Wiley-VCH.

    图 4  三元正交激发发射体系的结构设计示意图

    Figure 4.  Schematic diagram of structure design for ternary orthogonal excitation-emission systems

    图 5  基于正交三基色上转换发光的三元正交激发发射体系。(a)具有不依赖于激发功率密度的高色纯度红-绿-蓝三基色正交发光的NaYF4:Yb/Tm@NaYF4@NaYF4:Er/Ho@NaYF4@ NaYF4:Nd/Yb/Er@NaYF4:Nd五层核壳纳米结构示意图和在1560/808/980 nm三元激发下的发射光谱及对应的发光照片[58];(b) 具有不依赖于激发功率密度的正交三基色发光的LiYbF4:Tm@LiGdF4@LiGdF4:Yb/Er@LiYF4:Nd/Yb@LiGdF4@ LiErF4:Tm@LiGdF4六层核壳纳米结构示意图和在1532/980/800 nm三元激发下的发射光谱及对应的发光照片[61];(c)具有不依赖于激发功率密度的正交三基色发光的NaErF4@NaYF4@NaGdF4:Yb/Er@NaGdF4:Yb@ NaGdF4:Nd/Yb@NaYF4@NaGdF4:Yb/Tm@NaYF4七层核壳纳米结构示意图和在808/980/1550 nm三元激发下的发射光谱及对应的发光照片[63]。 (a)转载自文献[58],版权所有(2021)美国化学学会; (b)转载自文献[61],版权所有(2021)美国化学学会; (c)转载自文献[63],版权所有(2021)自然出版集团

    Figure 5.  Ternary orthogonal excitation-emission systems for orthogonal three-primary-color upconversion luminescence. (a)Schematic illustration of core/quintuple-shell NaYF4:Yb/Tm@NaYF4@NaYF4:Er/Ho @NaYF4@NaYF4:Nd/Yb/Er@NaYF4:Nd with excitation power density-independent red-green-blue high-pure three-primary-color orthogonal emissions and its corresponding emission spectra and photographs under 1532/980/800 nm ternary excitations[58]; (b)Schematic illustration of core/sextuple-shell LiYbF4:Tm@LiGdF4@ LiGdF4:Yb/Er@LiYF4:Nd/Yb@LiGdF4@LiErF4:Tm@LiGdF4 with excitation power density-independent orthogonal three-primary-color luminescence and its corresponding emission spectra and photographs under 1532/980/800 nm ternary excitations[61]; (d) Transmission electron microscopy image and schematic illustration of core/septuple-shell NaErF4@NaYF4@NaGdF4:Yb/Er@NaGdF4:Yb@NaGdF4:Nd/Yb@NaYF4@NaGdF4:Yb/Tm @NaYF4 with excitation power density-independent orthogonal three-primary-color luminescence and its corresponding photographs under 1532/808/980 nm ternary excitations[63]. (a) Reproduced with permission ref. [58]. Copyright 2021, American Chemical Society; (b) Reproduced with permission ref. [61]. Copyright 2021, American Chemical Society; (c) Reproduced with permission ref. [63]. Copyright 2021, Nature Publishing Group.

    图 6  正交激发发射体系的应用领域

    Figure 6.  Applications of orthogonal excitation-emission systems

    图 7  正交激发发射体系在光学存储、安全防伪及显示领域的应用。(a)二元正交激发发射体系用于近红外光驱动下的光学数据存储[50];(b)二元正交激发发射体系用于多级防伪[48];(c)三元正交激发发射体系用于信息的加密与解密[58];(d)三元正交激发发射体系用于高级防伪[70];(e)二元正交激发发射体系用于多维度防伪[49];(f)三元正交激发发射体系用于二维彩色显示[61]。(a)转载自文献[50],版权所有(2018)威立出版集团; (b)转载自文献[48],版权所有(2016)威立出版集团; (c)转载自文献[58],版权所有(2021)美国化学学会;(d)转载自文献[70],版权所有(2022)美国化学学会;(e)转载自文献[49],版权所有(2017)美国化学学会;(f)转载自文献[61],版权所有(2021)美国化学学会;

    Figure 7.  Typically applications of orthogonal excitation-emission systems in the fields of optical storage, security anticounterfeiting and displays. (a) Binary orthogonal excitation-emission system for NIR-guided optical data storage[50]; (b) Binary orthogonal excitation-emission system for multi-level anti-counterfeiting[48]; (c) Ternary orthogonal excitation-emission system for information encryption and decryption[58]; (d) Ternary orthogonal excitation-emission system for advanced anti-counterfeiting[70]; (e) Binary orthogonal excitation-emission system for multi-dimensional anti-counterfeiting[49]; (f) Ternary orthogonal excitation-emission system for 2D color display[61]. (a) Reproduced with permission ref. [50]. Copyright 2018, Wiley-VCH; (b) Reproduced with permission ref. [48]. Copyright 2016, Wiley-VCH; (c) Reproduced with permission ref. [58]. Copyright 2021, American Chemical Society; (d) Reproduced with permission ref. [70]. Copyright 2022, American Chemical Society; (e) Reproduced with permission ref. [49]. Copyright 2017, American Chemical Society; (f) Reproduced with permission ref. [61]. Copyright 2021, American Chemical Society

    图 8  正交激发发射体系在传感及生物医学领域的应用。(a)二元正交激发发射体系用于对指纹内残留物TNT的检测[56];(b)二元正交激发发射体系用于对黄曲霉毒素B1的检测[65];(c)二元正交激发发射体系用于超分辨成像[51];(d) 二元正交激发发射体系用于成像引导的光动力/化疗联合治疗[48]。(a)转载自文献[56],版权所有(2020)威立出版集团; (b)转载自文献[65],版权所有(2021)美国化学学会; (c)转载自文献[51],版权所有(2021)皇家化学学会;(d)转载自文献[48],版权所有(2016)威立出版集团

    Figure 8.  Typically applications of orthogonal excitation-emission systems in the fields of sensing and biomedicine. (a) Binary orthogonal excitation-emission system for the detection of TNT residues in the fingerprint[56]; (b) Binary orthogonal excitation-emission system for the detection of aflatoxin B1[65]; (c) Binary orthogonal excitation-emission system for super-resolution image[51]; (d) Binary orthogonal excitation-emission system for imaging-guided combined photodynamic therapy/ chemotherapy[48]. (a) Reproduced with permission ref. [56]. Copyright 2020, Wiley-VCH; (b) Reproduced with permission ref. [65]. Copyright 2021, American Chemical Society; (c) Reproduced with permission ref. [51]. Copyright 2021, Royal Society of Chemistry; (d) Reproduced with permission ref. [48]. Copyright 2016, Wiley-VCH.

    表  1  正交激发发射体系类型及研究进展与应用前景汇总

    Table  1.   Summary of orthogonal excitation-emission system types, research progress and application prospects

    Core-shell nanomaterials with orthogonal excitations-emissionsOrthogonal excitation typeSensitizer-ActivatorLuminescence color@
    Excitation wavelength
    Application fieldsReference/PublicationYear
    NaGdF4:Yb/Tm@NaGdF4@NaYbF4:Nd@Na(Yb,Gd)F4:Ho@NaGdF4
    BinaryYb3+-Tm3+/
    Nd3+-Yb3+-Ho3+
    UV/blue@980 nm
    Green@808 nm
    [41]
    2013
    NaYF4:Nd/Yb/Tm@NaYF4:Nd@NaYF4@NaYF4:Yb/Er
    BinaryNd3+-Yb3+-Tm3+/
    Yb3+→Er3+
    UV/blue@808 nm
    Green@980 nm
    Photo-switching[33]
    2014
    NaGdF4:Yb,Er@NaYF4:Yb@NaGdF4:Yb,Nd@NaYF4@NaGdF4:Yb,Tm@NaYF4
    BinaryNd3+-Yb3+-Er3+/
    Yb3+-Tm3+
    Green@796 nm
    UV/blue@980 nm
    anticounterfeiting/PDT/CT[48]
    2016
    NaGdF4:Yb,Er@NaYF4@ NaYF4:Yb,Tm@NaYbF4:Nd@NaYF4
    BinaryYb3+-Er3+/
    Nd3+-Yb3+-Tm3+
    Green@980 nm
    UV/blue@808 nm
    Fingerprint imaging[49]
    2017
    NaYF4:Er@NaYF4@NaYF4:Yb/Tm@NaYF4

    BinaryEr3+/
    Yb3+-Tm3+
    Green@1532 nm
    UV/blue@980 nm
    Optical data storage[50]
    2018
    NaYF4:Er@NaYF4@NaYF4:Yb/Tm

    BinaryEr3+/
    Yb3+-Tm3+
    Green@808 nm
    Blue@980 nm
    Super-resolution image[51]
    2018
    NaErF4@NaYF4@NaYbF4:Tm @NaYF4

    BinaryEr3+/
    Yb3+-Tm3+
    Red@800 nm
    Blue@980 nm
    Imaging-guided PDT[52]
    2018
    NaErF4:Tm@NaYF4@NaYF4: Yb/Ho@NaYF4

    BinaryEr3+-Tm3+/
    Yb3+-Ho3+
    Red@808/1550 nm
    Green@980 nm
    [20]
    2019
    NaErF4:Tm@NaYF4@NaYF4: Yb/Tm@NaYF4

    BinaryEr3+-Tm3+/
    Yb3+-Tm3+
    Red@808/1550 nm
    Blue@980 nm
    [20]
    2019
    NaErF4:Yb/Tm@NaYF4:Yb@NaNdF4:Yb

    BinaryEr3+-Tm3+/
    Nd3+-Yb3+-Er3+
    Red@980 nm
    Green@808 nm
    Photoactivation/detection[55,65]
    2019
    NaYF4:Yb/Er/Mn@NaYF4:Yb@NaNdF4:Yb

    BinaryYb3+-Er3+-Mn2+/Nd3+-Yb3+-Er3+Red@980 nm
    Green@808 nm
    Latent fingerprint
    sensing
    [56]
    2020
    NaGdF4:Yb,Er@NaYF4@NaYF4:Yb,Tm@NaYbF4:Nd@NaYF4
    BinaryYb3+-Er3+/ Nd3+-Yb3+-Tm3+Green@980 nm
    UV/blue@808 nm
    Tumor cell recognition/ PDT[74]
    2020
    NaErF4:Yb/Tm@NaYbF4Binary

    Er3+-Tm3+/
    Yb3+-Er3+
    Green@808 nm
    Red@980 nm
    Information
    security
    [57]
    2021
    NaYF4:Yb/Tm@NaYF4@NaYF4:Er/Ho@NaYF4@NaYF4:Nd/Yb/Er@NaYF4:Nd
    TernaryYb3+-Tm3+/
    Er3+-Ho3+/ Nd3+-Yb3+-Er3+
    UV/blue@980 nm Red
    @1560 nm Green@808 nm
    Information
    Security/ anticounterfeiting
    [58-60,67-70]
    2021/2022
    LiYbF4:Tm@LiGdF4@LiGdF4:Yb/Er@LiYF4:Nd/Yb@LiGdF4@LiErF4:Tm@LiGdF4
    TernaryYb3+-Tm3+/
    Nd3+-Yb3+-Er3+/ Er3+-Tm3+
    UV/blue@980 nm
    Green@808 nm
    Red@1532 nm
    2D full-color display[61]
    2021
    NaErF4@NaYF4@NaGdF4:Yb/Er@NaGdF4:Yb@NaGdF4:Nd/Yb@NaYF4@NaGdF4:Yb/Tm@NaYF4
    TernaryEr3+/ Nd3+-Yb3+-Er3+/ Yb3+-Tm3+Red@1532 nm
    Green@808 nm
    Blue@980 nm
    Neuronal
    population
    [63]
    2021
    NaYF4:Yb/Tm@NaYF4:Yb/Nd@NaLuF4@NaYF4:Yb/Er@NaLuF4@NaErF4:Tm@NaLuF4
    Ternary

    Nd3+-Yb3+-Tm3+/ Yb3+-Er3+/ Er3+-Tm3+Blue@808 nm
    Green@980 nm
    Red@1532 nm
    Multiplexed
    detection
    [73]
    2021
    NaErF4:Tm@NaYF4@NaYF4:Yb/Ho@NaYF4:Nd/Yb@NaYF4@NaYbF4:Tm@ NaYF4:YbTernaryEr3+-Tm3+/ Nd3+-Yb3+-Ho3+/ Yb3+-Tm3+Red@1550 nm
    Green@808 nm
    UV/blue@980 nm
    Flexible display/ anticounterfeiting[62]
    2022
    下载: 导出CSV
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  • 录用日期:  2022-08-03
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