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Charge transfer induced surface enhanced Raman scattering of single crystal and polycrystal perovskites

YU Zhi YU Wei-li GUO Chun-lei

于治, 于伟利, 郭春雷. 基于电荷转移的钙钛矿单晶和多晶材料表面增强拉曼散射研究[J]. 中国光学, 2019, 12(5): 952-963. doi: 10.3788/CO.20191205.0952
引用本文: 于治, 于伟利, 郭春雷. 基于电荷转移的钙钛矿单晶和多晶材料表面增强拉曼散射研究[J]. 中国光学, 2019, 12(5): 952-963. doi: 10.3788/CO.20191205.0952
YU Zhi, YU Wei-li, GUO Chun-lei. Charge transfer induced surface enhanced Raman scattering of single crystal and polycrystal perovskites[J]. Chinese Optics, 2019, 12(5): 952-963. doi: 10.3788/CO.20191205.0952
Citation: YU Zhi, YU Wei-li, GUO Chun-lei. Charge transfer induced surface enhanced Raman scattering of single crystal and polycrystal perovskites[J]. Chinese Optics, 2019, 12(5): 952-963. doi: 10.3788/CO.20191205.0952

基于电荷转移的钙钛矿单晶和多晶材料表面增强拉曼散射研究

doi: 10.3788/CO.20191205.0952
基金项目: 国家重点研发计划"增材制造与激光制造"重点专项项目(No.2017YFB1104700);国家自然科学基金(No.61705227,No.61774155,No.11774340);吉林省科技发展计划项目(No.20180414019GH);中国科学院国际合作局对外合作重点项目(No.181722KYSB20160015)
详细信息
  • 中图分类号: O433.5

Charge transfer induced surface enhanced Raman scattering of single crystal and polycrystal perovskites

Funds: Supported by National Key R&D Program of China(No.2017YFB1104700); National Natural Science Foundation(No.61705227, No.61774155, No.11774340); Jilin Provincial Science & Technology Development Project (No.20180414019GH); Scientific Research Project of the Chinese Academy of Sciences(No.QYZDB-SSW-SYS038); The Key Program of the International Partnership Program of CAS(No.181722KYSB20160015)
More Information
    Author Bio:

    YU Zhi (1988-), Ph.D, Assistant Professor, Changchun Institute of Optics, Fine Mechanics and Physics, Chinese Academy of Sciences.His research interests are on interfacial charge transfer based Surface enhanced Raman scattering.E-mail:zhiyu@ciomp.ac.cn

    YU Wei-li (1979-), Ph.D, Associate Professor, Changchun Institute of Optics, Fine Mechanics and Physics, Chinese Academy of Sciences.His research interests are on functional nanomaterials researches and its light energy related applications.E-mial:weili.yu@ciomp.ac.cn

    GUO Chun-lei (1971-), Ph.D, Professor, Changchun Institute of Optics, Fine Mechanics and Physics, Chinese Academy of Sciences.His research interests are on laser-matter interactions at high intensities, nano-photonics, femtosecond laser surface nano and microstructuring, and surface plasmonics.E-mail:guo@optics.rochester.edu

    Corresponding author: YU Wei-li, E-mial:weili.yu@ciomp.ac.cnGUO Chun-lei, E-mail:guo@optics.rochester.edu
  • 摘要: 近年来,钙钛矿作为一种新型的能源材料受到了众多学者的广泛关注。由于其具有较高的吸收系数、载流子迁移率以及扩散长度而被应用到光电器件中,例如:太阳能电池、光电探测器、场效晶体管以及发光二极管等。器件界面电荷转移过程则是影响钙钛矿材料性能的一个关键因素,在本工作中,利用表面增强拉曼光谱,研究了钙钛矿材料的电荷转移性质;制备了MAPbCl3钙钛矿单晶以及多晶薄膜,并在其表面沉积一层酞菁铜分子;随后,在酞菁铜表面再次沉积一层银膜。试图通过表面增强拉曼光谱(SERS)技术研究钙钛矿-钛菁铜界面的电荷转移过程以及表面银膜所产生的表面等离子体共振对于界面电荷转移及SERS性质的影响。研究结果表明,钙钛矿材料与钛菁铜分子能级匹配,且对于532 nm激发波长的激光具有良好的响应;532 nm激光能够诱导界面电荷转移过程的发生。同时,表面沉积的银膜可以进一步放大SERS信号。这主要是由于银膜的表面等离子体共振能够增强电荷分离,提高电荷转移效率,同时其表面产生的较强的电磁场,可以进一步增强钛菁铜分子的Raman信号强度。
  • Figure  1.  SEM image and EDS analysis of MAPbCl3perovskite polycrystalline thin film(a) and single crystal(b)

    Figure  2.  XRD spectra of single crystal and polycrystalline perovskite

    Figure  3.  UV-Vis spectra of single crystal perovskite(a) and polycrystal perovskite(b) before and after modification with MPY molecules compared with the spectra of MPY molecules dissolved in CH2Cl2

    Figure  4.  Raman spectra of MPY molecules adsorbed on the surface of polycrystalline and single crystal perovskiteS

    Figure  5.  Raman spectra of MPY powder, MPY on polycrystalline perovskite, MPY on silver film and MPY on the polycrystalline perovskite deposited with a silver film

    Figure  6.  Raman spectra of CuPc adsorbed on the perovskite single crystal and polycrystalline compared with the Raman signal of CuPc powder

    Figure  7.  SERS spectra of CuPc adsorbed on single crystal and polycrystalline perovskite under the excitation lasers of 473, 532 and 785 nm

    Figure  8.  Laser induced CT processes under the excitation laser of 473, 532 and 785 nm

    Figure  9.  SERS spectra of CuPc adsorbed on single crystal and polycrystalline film after the addition of silver film

    Figure  10.  SERS spectra of CuPc-perovskite, CuPc-Ag, perovskite-CuPc-Ag and the Raman spectra of CuPc powder

    Table  1.   Band assignment of the CuPc molecules

    CuPc Powder/cm-1 CuPc-Perovskite/cm-1 Bands Assignments
    594 594 A1g
    678 678 B1g, in plane full symmetric nonmetal bound N-M stretch and outer ring stretches
    745 745 B2g, in plane ring symmetric N-M stretch
    828 828 A1g, in plane full symmetric N-M stretch
    951 951
    1 036 1 037 B1g
    1 140 1 140 A1g, in plane symmetric N-M-N bend
    1 334 1 339 B1g, in plane full symmetric N-C stretch and ring C-C stretch
    1 445 1 449 B2g, in plane ring symmetric outer ring C-C stretch
    1 518 1 525 B2g, ring C-C stretch and in plane ring symmetric non metal bound N-C stretch
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  • 收稿日期:  2019-01-07
  • 修回日期:  2019-02-28
  • 刊出日期:  2019-10-01

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