远程紫外拉曼光谱检测技术研究进展

何玉青; 魏帅迎; 郭一新; 赵曼; 金伟其; 任林茂

doi:10.3788/CO.20191206.1249

远程紫外拉曼光谱检测技术研究进展

doi: 10.3788/CO.20191206.1249

何玉青^1, ,,
魏帅迎¹,
郭一新¹,
赵曼¹,
金伟其¹,
任林茂^{1, 2}

1.
北京理工大学光电学院光电成像技术与系统教育部重点实验室, 北京 100081
2.
铁道警察学院, 河南郑州 450053

基金项目:

国家重点研发计划 2016YFC0800900

河南省科技攻关项目 192102310515

详细信息

作者简介:
何玉青(1977—), 女, 河北无极人, 副教授, 2003年于北京理工大学获得博士学位, 主要从事光谱检测与分析、光电成像技术与信息处理等方面的研究。E-mail:yuqinghe@bit.edu.cn

中图分类号: TN23
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出版历程
- 收稿日期: 2018-12-10
- 修回日期: 2019-01-23
- 刊出日期: 2019-12-01

Research progress of remote detection with ultraviolet Raman spectroscopy

1.
MOE Key Laboratory of Photoelectronic Imaging Technology and System, School of Optics and Photonics, Beijing Institute of Technology, Beijing 100081, China
2.
Railway Police College, Zhengzhou 450053, China

Funds:

National Key Research and Development Plan of China 2016YFC0800900

Key Scientific and Technological Projects in Henan 192102310515

More Information

Corresponding author: HE Yu-qing, E-mail:yuqinghe@bit.edu.cn

摘要

摘要: 远距离检测主要用于人类不宜或不易接触的物品检测，紫外拉曼光谱法是一种比较有效的远距离危险物品检测方法，在反恐、禁毒和食品安全等领域具有广泛的应用前景。本文在分析远程拉曼光谱检测技术基本原理的基础上，总结了紫外拉曼光谱检测技术的优势，对远程紫外拉曼光谱检测技术的现状进行综合分析。从激光器发射、光学接收系统、光谱接收、光谱处理等方面分析了不同模块关键技术及研究现状，分析了远程紫外拉曼光谱检测技术的研究难点和发展趋势。
- 紫外 /
- 拉曼光谱 /
- 远程探测 /
- 光谱处理
Abstract: Ultraviolet Raman spectroscopy is a relatively effective and promising method for the detection of long-distance dangerous items. It has broad applications in the fields of anti-terrorism, drug control and food safety. Based on an analysis of the basic principles of Raman spectroscopy remote detection, this paper summarizes the advantages of ultraviolet Raman detection technology and comprehensively analyzes its research status. The module's design methods, key techniques and existing problems are analyzed from the perspective of laser emission, optical receiving system, spectral reception and spectral processing. The research difficulties and development trends of remote detection technology with ultraviolet Raman spectroscopy are summarized.
- ultraviolet /
- Raman spectroscopy /
- remote detection /
- spectral processing

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图 1 KNO₃拉曼光谱

Figure 1. Raman spectrum of KNO₃

下载: 全尺寸图片幻灯片

图 2 远程拉曼光谱检测系统

Figure 2. Remote Raman spectroscopy detection system

下载: 全尺寸图片幻灯片

图 3 拉曼响应与荧光光谱(Laser Line为激光发射源)

Figure 3. Raman response and fluorescence spectrum (Laser Line is the response of the laser source)

下载: 全尺寸图片幻灯片

图 4 发射系统和接收系统几何关系

Figure 4. Relationship between the transmitting system and the receiving system

下载: 全尺寸图片幻灯片

表 1 常规紫外拉曼系统激光光源参数及探测目标参数

Table 1. Laser source and target parameters of conventional UV Raman system

光源参数		目标参数			参考文献
光源波长/nm	光源能量	目标距离/m	目标类型	尺寸或含量	参考文献
228	＞0.5 μJ/pulse，5 mW, 0~10 kHz	1~10	explosives	1 mm×1 mm~200 mm×200 mm	^[15]
229	CW, 4.3 mW	2.3	PETN, AN	10~1 000 μg/cm²	^[46]
262	3 mW/cm², 500 Hz	1~10	sucrose等	/	^[23]
266	3 mJ/cm², 20 Hz	6~10	AN	100 μg/cm²	^[17]
266	10.3 mJ/pulse, 10 Hz	18	KClO₃, calcite	/	^[24]
266	23.5 mJ/pulse, 10 Hz	42	Teflon	2 mm厚, 30 mm×30 mm的立方体	^[19]
266	8 mJ/pulse, 30 Hz	533	Teflon/cyclohexane, acetonitrile	850 g/m²	^[5]
355	13 mW, 100 Hz	6	有机物等	/	^[41]
355	1.5 mJ/pulse, 1 kHz	10	AN	单个AN微粒直径＜300 μm	^[18]
220, 232, 248, 250, 260等波长可调	3~10 mJ/pulse, 10 Hz	13	NM, AN	/	^[12]
其中CW为连续激光器，表中的“/”代表文献中未提到该项参数.

下载: 导出CSV

表 2 常规光学接收系统参数及目标距离

Table 2. Conventional optical receiving system parameters and target distance

光学接收系统					目标距离/m	参考文献
几何结构	光学结构	直径	F数	焦距/mm	目标距离/m	参考文献
coaxial	Cassegrain	1.6 in.	f/15	/	533	^[5]
coaxial	Cassegrain	203 mm	10	2 032	22	^[8]
coaxial	Cassegrain	203.2 mm	/	/	6	^[41]
coaxial	Schmidt-Cassegrain	200 mm	/	300	10	^[18]
coaxial	Newtonian	6 in.	f/4	/	30	^[6]
coaxial	Newtonian	300 mm	/	1 000	6~10	^[17]
coaxial	Richey Chretien	12.4 in.	f/9.1	/	18	^[24]
coaxial	Gregorian	6 in.	/	/	/	^[34]
off-axis	Cassegrain	/	/	/	13	^[12]
/	Maksutov-Cassegrain	3.5 in.	/	/	2.3	^[46]
/	Schmidt-Cassegrain	8 in.	/	/	30	^[22]

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表 3 现有远程紫外拉曼光谱检测系统光谱接收模块参数

Table 3. Spectral receiver module parameters of current remote ultraviolet Raman spectroscopy system

光谱分辨率/cm^-1	光栅分辨率	光谱范围/cm^-1	信噪比	探测器	参考文献
3	300 grooves/mm, 300 nm	/	/	gated ICCD	^[24]
4.5	600、2 400、1 800 grooves/mm	800~1800, 2 500-4 000	/	ICCD	^[10]
10	/	/	/	gated ICCD	^[18]
11	2 400 grooves/mm, 250 nm	/	5:1	gated ICCD	^[5]
15	/	/	13:1	gated ICCD	^[23]
22	2 380 grooves/mm	650~3 650	/	gated ICCD	^[6]
30	3 600 line/mm	＜3443	/	ICCD	^[34]
40	1 200, 2 400 grooves/mm	100~2 100, 300~4 300	/	gated ICCD	^[41]

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