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远程紫外拉曼光谱检测技术研究进展

何玉青 魏帅迎 郭一新 赵曼 金伟其 任林茂

何玉青, 魏帅迎, 郭一新, 赵曼, 金伟其, 任林茂. 远程紫外拉曼光谱检测技术研究进展[J]. 中国光学(中英文), 2019, 12(6): 1249-1259. doi: 10.3788/CO.20191206.1249
引用本文: 何玉青, 魏帅迎, 郭一新, 赵曼, 金伟其, 任林茂. 远程紫外拉曼光谱检测技术研究进展[J]. 中国光学(中英文), 2019, 12(6): 1249-1259. doi: 10.3788/CO.20191206.1249
HE Yu-qing, WEI Shuai-ying, GUO Yi-xin, ZHAO Man, JIN Wei-qi, REN Lin-mao. Research progress of remote detection with ultraviolet Raman spectroscopy[J]. Chinese Optics, 2019, 12(6): 1249-1259. doi: 10.3788/CO.20191206.1249
Citation: HE Yu-qing, WEI Shuai-ying, GUO Yi-xin, ZHAO Man, JIN Wei-qi, REN Lin-mao. Research progress of remote detection with ultraviolet Raman spectroscopy[J]. Chinese Optics, 2019, 12(6): 1249-1259. doi: 10.3788/CO.20191206.1249

远程紫外拉曼光谱检测技术研究进展

doi: 10.3788/CO.20191206.1249
基金项目: 

国家重点研发计划 2016YFC0800900

河南省科技攻关项目 192102310515

详细信息
    作者简介:

    何玉青(1977—), 女, 河北无极人, 副教授, 2003年于北京理工大学获得博士学位, 主要从事光谱检测与分析、光电成像技术与信息处理等方面的研究。E-mail:yuqinghe@bit.edu.cn

  • 中图分类号: TN23

Research progress of remote detection with ultraviolet Raman spectroscopy

Funds: 

National Key Research and Development Plan of China 2016YFC0800900

Key Scientific and Technological Projects in Henan 192102310515

More Information
  • 摘要: 远距离检测主要用于人类不宜或不易接触的物品检测,紫外拉曼光谱法是一种比较有效的远距离危险物品检测方法,在反恐、禁毒和食品安全等领域具有广泛的应用前景。本文在分析远程拉曼光谱检测技术基本原理的基础上,总结了紫外拉曼光谱检测技术的优势,对远程紫外拉曼光谱检测技术的现状进行综合分析。从激光器发射、光学接收系统、光谱接收、光谱处理等方面分析了不同模块关键技术及研究现状,分析了远程紫外拉曼光谱检测技术的研究难点和发展趋势。

     

  • 图 1  KNO3拉曼光谱

    Figure 1.  Raman spectrum of KNO3

    图 2  远程拉曼光谱检测系统

    Figure 2.  Remote Raman spectroscopy detection system

    图 3  拉曼响应与荧光光谱(Laser Line为激光发射源)

    Figure 3.  Raman response and fluorescence spectrum (Laser Line is the response of the laser source)

    图 4  发射系统和接收系统几何关系

    Figure 4.  Relationship between the transmitting system and the receiving system

    表  1  常规紫外拉曼系统激光光源参数及探测目标参数

    Table  1.   Laser source and target parameters of conventional UV Raman system

    光源参数 目标参数 参考文献
    光源波长/nm 光源能量 目标距离/m 目标类型 尺寸或含量
    228 >0.5 μJ/pulse,5 mW, 0~10 kHz 1~10 explosives 1 mm×1 mm~200 mm×200 mm [15]
    229 CW, 4.3 mW 2.3 PETN, AN 10~1 000 μg/cm2 [46]
    262 3 mW/cm2, 500 Hz 1~10 sucrose等 / [23]
    266 3 mJ/cm2, 20 Hz 6~10 AN 100 μg/cm2 [17]
    266 10.3 mJ/pulse, 10 Hz 18 KClO3, calcite / [24]
    266 23.5 mJ/pulse, 10 Hz 42 Teflon 2 mm厚, 30 mm×30 mm的立方体 [19]
    266 8 mJ/pulse, 30 Hz 533 Teflon/cyclohexane, acetonitrile 850 g/m2 [5]
    355 13 mW, 100 Hz 6 有机物等 / [41]
    355 1.5 mJ/pulse, 1 kHz 10 AN 单个AN微粒直径<300 μm [18]
    220, 232, 248, 250, 260等波长可调 3~10 mJ/pulse, 10 Hz 13 NM, AN / [12]
        其中CW为连续激光器,表中的“/”代表文献中未提到该项参数.
    下载: 导出CSV

    表  2  常规光学接收系统参数及目标距离

    Table  2.   Conventional optical receiving system parameters and target distance

    光学接收系统 目标距离/m 参考文献
    几何结构 光学结构 直径 F 焦距/mm
    coaxial Cassegrain 1.6 in. f/15 / 533 [5]
    coaxial Cassegrain 203 mm 10 2 032 22 [8]
    coaxial Cassegrain 203.2 mm / / 6 [41]
    coaxial Schmidt-Cassegrain 200 mm / 300 10 [18]
    coaxial Newtonian 6 in. f/4 / 30 [6]
    coaxial Newtonian 300 mm / 1 000 6~10 [17]
    coaxial Richey Chretien 12.4 in. f/9.1 / 18 [24]
    coaxial Gregorian 6 in. / / / [34]
    off-axis Cassegrain / / / 13 [12]
    / Maksutov-Cassegrain 3.5 in. / / 2.3 [46]
    / Schmidt-Cassegrain 8 in. / / 30 [22]
    下载: 导出CSV

    表  3  现有远程紫外拉曼光谱检测系统光谱接收模块参数

    Table  3.   Spectral receiver module parameters of current remote ultraviolet Raman spectroscopy system

    光谱分辨率/cm-1 光栅分辨率 光谱范围/cm-1 信噪比 探测器 参考文献
    3 300 grooves/mm, 300 nm / / gated ICCD [24]
    4.5 600、2 400、1 800 grooves/mm 800~1800, 2 500-4 000 / ICCD [10]
    10 / / / gated ICCD [18]
    11 2 400 grooves/mm, 250 nm / 5:1 gated ICCD [5]
    15 / / 13:1 gated ICCD [23]
    22 2 380 grooves/mm 650~3 650 / gated ICCD [6]
    30 3 600 line/mm <3443 / ICCD [34]
    40 1 200, 2 400 grooves/mm 100~2 100, 300~4 300 / gated ICCD [41]
    下载: 导出CSV
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  • 收稿日期:  2018-12-10
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