激光诱导击穿光谱技术及应用研究进展

侯冠宇; 王平; 佟存柱

doi:10.3788/CO.20130604.0490

激光诱导击穿光谱技术及应用研究进展

doi: 10.3788/CO.20130604.0490

1.
南京林业大学化学工程学院, 江苏南京 210037;
2.
中国科学院长春光学精密机械与物理研究所发光学及应用国家重点实验室, 吉林长春 130033

基金项目:

国家自然科学基金面上项目(No.31270680,No.61076064);江苏省"六大高峰人才"资助项目(No.2011-XCL-018);江苏高校优势学科建设工程资助项目

详细信息

作者简介:
侯冠宇(1988-),男,吉林四平人,2012年于南京林业大学化工学院获得学士学位,主要从事环境污染物激光光谱检测研究。E-mail:jumjim88@126.com;王平(1962-),女,江苏扬州人,教授,博士生导师,1984年、2007年于南京大学分别获得学士、博士学位,主要从事环境污染物的评价与治理、工业水处理剂研制与开发等方面的研究。E-mail:wp_lh@yahoo.com.cn;佟存柱(1976-),男,吉林伊通人,研究员,博士生导师,1999年于重庆大学获得学士学位,2005年于中国科学学院半导体研究所获得博士学位,曾先后在新加坡南洋理工大学和加拿大多伦多大学从事博士后研究工作,目前在中国科学院长春光学精密机械与物理研究所任"百人计划"研究员,主要从事大功率半导体激光器的研究。E-mail:tongcz@ciomp.ac.cn

侯冠宇(1988-),男,吉林四平人,2012年于南京林业大学化工学院获得学士学位,主要从事环境污染物激光光谱检测研究。E-mail:jumjim88@126.com;王平(1962-),女,江苏扬州人,教授,博士生导师,1984年、2007年于南京大学分别获得学士、博士学位,主要从事环境污染物的评价与治理、工业水处理剂研制与开发等方面的研究。E-mail:wp_lh@yahoo.com.cn;佟存柱(1976-),男,吉林伊通人,研究员,博士生导师,1999年于重庆大学获得学士学位,2005年于中国科学学院半导体研究所获得博士学位,曾先后在新加坡南洋理工大学和加拿大多伦多大学从事博士后研究工作,目前在中国科学院长春光学精密机械与物理研究所任"百人计划"研究员,主要从事大功率半导体激光器的研究。E-mail:tongcz@ciomp.ac.cn

侯冠宇(1988-),男,吉林四平人,2012年于南京林业大学化工学院获得学士学位,主要从事环境污染物激光光谱检测研究。E-mail:jumjim88@126.com;王平(1962-),女,江苏扬州人,教授,博士生导师,1984年、2007年于南京大学分别获得学士、博士学位,主要从事环境污染物的评价与治理、工业水处理剂研制与开发等方面的研究。E-mail:wp_lh@yahoo.com.cn;佟存柱(1976-),男,吉林伊通人,研究员,博士生导师,1999年于重庆大学获得学士学位,2005年于中国科学学院半导体研究所获得博士学位,曾先后在新加坡南洋理工大学和加拿大多伦多大学从事博士后研究工作,目前在中国科学院长春光学精密机械与物理研究所任"百人计划"研究员,主要从事大功率半导体激光器的研究。E-mail:tongcz@ciomp.ac.cn

通讯作者:
王平

中图分类号: O433.54;O657.319
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出版历程
- 收稿日期: 2013-04-11
- 修回日期: 2013-06-13
- 刊出日期: 2013-08-10

Progress in laser-induced breakdown spectroscopy and its applications

1.
College of Chemical Engineering, Nanjing Forestry University, Nanjing 210037, China;
2.
State Key Laboratory of Luminescence and Applications, Changchun Institute of Optics, Fine Mechanics and Physics, Chinese Academy of Sciences, Changchun 130033, China

摘要

摘要: 激光诱导击穿光谱(LIBS)技术是一种基于原子发射光谱学的元素定性、定量检测手段。本文介绍了LIBS技术的原理、应用方式、检测元素种类及检测极限;综述了该项技术在固体、液体、气体组分检测方面的技术发展,以及在环境检测、食品安全、生物医药、材料、军事、太空领域的应用进展。最后,提出了高功率、高稳定的激光光源和准确的定量分析方法是LIBS技术目前所面临的问题和挑战。
- 激光诱导击穿光谱 /
- 激光产生等离子体 /
- 元素分析 /
- 检测限
Abstract: Laser-induced Breakdown Spectroscopy(LIBS) based on atomic emission spectral technology is a kind of convenient and sensitive approach for the qualitative and quantitative detection of elements. In this paper, the mechanism, detecting element types, detection limit and the recent progress of LIBS technology are reviewed. The progress of LIBS technology in component testing for solid, liquid and gas samples is expounded in detail. The applications of LIBS in the environment test, food security, biological and medicines, material sciences, military and space fields are also presented. Finally, the challenges and problems for the LIBS technology in high power and stable laser sources and accurately quantitative analysis method are discussed.
- laser-induced breakdown spectroscopy /
- laser-induced plasmon /
- element analysis /
- detection limit

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参考文献(1)

[1] 叶继飞,洪延姬,王广宇,等. 激光等离子体微推进技术的研究进展[J]. 中国光学,2011,4(4):319-326. YE J F,HONG Y J,WANG G Y,et al.. Research progress in micro-laser plasma propulsion[J]. Chinese Optics,2011,4(4):319-326.(in Chinese) [2] 任玉,李付锦,董旭,等. 飞秒激光等离子体通道传导能量特性的研究进展[J]. 中国光学,2012,5(2):133-142. REN Y,LI F J,DONG X,et al.. Research of guiding energy with plasma channel induced by femtosecond laser in air[J]. Chinese Optics,2012,5(2):133-142.(in Chinese) [3] BRECH F,CROSS L. Optical microemission stimulated by a ruby laser[J]. Appl. Spectrosc.,1962,16:59-64. [4] DEBRAS-GUEDON J,LIODEC N. De l'utilisation du faisceau d'un amplificateur a ondes lumineuses par emission induite de rayonnement(laser a rubis), comme source energetique pour l'excitation des spectres d'emission des elements[J]. C.R. Acad. Sci.,1963,257:3336-3339. [5] MAKER P D,TERHUNE R W,SAVAGE C M. Optical third harmonic generatio [C]//Proc. of Third International Conference on Quantum Electronics, New York,USA,1964. [6] RUNGE E F,MINCK R W,BRYAN F R. Spectrochemical analysis using a pulsed laser source[J]. Spectrochim. Acta,1964,20:733. [7] CREMERS D A,RADZIEMSKI L J,LOREE T R. Spectrochemical analysis of liquids using the laser spark[J]. Appl. Spectrosc.,1984,38:721-729. [8] GRANT K J,PAUL G L,O'NEILL J A. Quantitative elemental analysis of iron ore by laser-induced breakdown spectroscopy[J]. Appl. Spectrosc.,1991,45:701-705. [9] KNIGHT A K,SCHERBARTH N L,CREMERS D A,et al.. Characterization of laser-induced breakdown spectroscopy(LIBS) for application to space exploration[J]. Appl. Spectrosc.,2000,54:331-340. [10] ZHANG SH H,YU X L. Laser induced breakdown spectroscopy for local equivalence ratio measurement of kerosene/air mixture at elevated pressure[J]. Opt. and Lasers in Eng.,2012,50:877-882. [11] MIROV S B,PITTB R E,DERGACHEV A. A novel laser breakdown spectrometer for environmental monitoring[J]. SPIE,1999,3855:34-41. [12] SONG Y,LEE Y,SNEDDON J. Recent developments in instrumentation for laser induced breakdown spectroscopy[J]. Appl. Spectrosc. Rev.,2002,37(1):89-117. [13] 王建伟,张娜珍,侯可勇,等. LIBS技术在土壤重金属污染快速测量中的应用[J]. 化学进展,2008,20:1165-1171. WANG J,ZHANG N,HOU K,LI H. Application of LIBS technology to the rapid measure of heavy metal contamination in soils[J]. Progress Chem.,2008,20:1165-1171.(in Chinese) [14] PATHAK A K,KUMAR R,SINGH V,et al.. Assessment of LIBS for spectrochemical analysis:a review[J]. Appl. Spectrosc. Rev.,2012,47:14-40. [15] ANNA P.M.MICHEL. Review:applications of single-shot laser-induced breakdown spectroscopy[J]. Spectrochimica Acta Part B,2010,65:185-191. [16] BOGAERTS A,CHEN ZH,AUTRIQUE D. Double pulse laser ablation and laser induced breakdown spectroscopy:a modeling investigation[J]. Spectrochimica Acta Part B,2008,63:746-754. [17] COLAO F,LAZIC V,FANTONI R,PERSHIN S. A comparison of single and double pulse laser-induced breakdown spectroscopy of aluminum samples[J]. Spectrochimica Acta Part B,2002,57:1167-1179. [18] CREMERS D A,CHINNI R C. Laser-Induced breakdown spectroscopy- capabilities and limitations[J]. Appl. Spectrosc. Rev.,2009,44:457-506. [19] TRAN M,SUN Q,SMITH B,et al.. Direct determination of trace elements in terephthalic acid by laser induced breakdown spectroscopy[J]. Analytica Chimica Acta,2000,419:153-158. [20] GIACOMO A D,DELL'AGLIO M,COLAO F,et al.. Double pulse LIBS in bulk water and on submerged bronze samples[J]. Appl. Surf. Sci.,2005,247:157-162. [21] GONDAL M A,HUSSAIN T,AHMED Z,et al.. Detection of contaminants in ore samples using laser-induced breakdown spectroscopy[J]. J. Environ. Sci. Health Pt. A,2007,42:879-887. [22] LAZIC V,JOVICEVIC S,FANTONI R,COLAO F. Efficient plasma and bubble generation underwater by an optimized laser excitation and its application for liquid analysis by Laser Induced Breakdown Spectroscopy[J]. Spectro-chim. Acta Part B:Atomic Spetroscopy,2007,62(12):1433-1442. [23] LIN D,WANG C,WU J,et al.. Laser-induced breakdown spectroscopy characterization of Al in different matrix[J]. Optolelectron. Lett.,2007,3(2):148-151. [24] PEARMAN W,SCAFFIDI J,ANGEL S M. Dual-pulse laser-induced breakdown spectroscopy in bulk aqueous solution with an orthogonal beam geometry[J]. Appl. Optics,2003,42:6085-6106. [25] 张谦,熊威,赵芳,等. 水环境重金属污染的激光诱导击穿光谱监测[J]. 环境科学与技术,2009,32: 98-101. ZHANG Q,XIONG W,ZHAO F,et al.. Monitoring of heavy metals pollution of water by laser-induced breakdown spectroscopy[J]. Environmental Science and Technology,2009,32:98-101.(in Chinese) [26] PICHAHCHY A E,CREMERS D A,FERRIS M J. Elemental analysis of metals under water using laser-induced breakdown spectroscopy[J]. Spectrochim. Acta Part B,1997,52:25-39. [27] YAMAMOTO K Y,CREMERS D A,FERRIS M J,et al.. Detection of metals in the environment using a portable laser-induced breakdown spectroscopy instrument[J]. Appl. Spectrosc.,1996,50:222-233. [28] GIACOMO A D,DELL'AGLIO M,CASAVOLA A,et al.. Elemental chemical analysis by double pulse laser induced breakdown spectroscopy on submerged target[J]. Anal. Bioanal. Chem.,2006,385:303-311. [29] 王琦,陈兴龙,余嵘华,等. 基于激光诱导击穿光谱技术对钢中Mn和Cr元素的定量分析[J]. 光谱学与光谱分析,2011,9: 2546-2551. WANG Q,CHEN X,YU R,et al.. Quantitative Analysis of Mn, Cr in steel based on laser-induced breakdown spectroscopy[J]. Spectroscopy and Spectral Analysis,2011,9:2546-2551.(in Chinese) [30] 李勇,陆继东,林兆祥,等. 应用激光诱导击穿光谱检测土壤中的铅[J]. 应用光学,2008,29(5):789-792. LI Y,LU J,LIN ZH X,et al.. Quantitative analysis of lead in soil by laser-induced breakdown spectroscopy[J]. J. Appl. Optics,2008,29(5):789-792.(in Chinese) [31] KOCH S,GAREN W,M?LLER M,et al.. Detection of chromium in liquids by laser induced breakdown spectroscopy(LIBS)[J]. Appl. Phys. A,2004,79:1071-1073. [32] ANZEN C,FLEIGE R,NOLL R,et al.. Analysis of small droplets with a new detector for liquid chromatography based on laser-induced breakdown spectroscopy[J]. Spectrochimica Acta Part B,2005,60:993-1001. [33] HUSSAIN T,GONDAL M A. Detection of toxic metals in waste water from dairy products plant using laser induced breakdown spectroscopy[J]. Bull. Environ Contam Toxicol,2008,80:561-565. [34] 王传辉,戴琳,等. AlCl₃水溶液的激光诱导击穿光谱研究[J]. 中国激光,2006,33(9):1190-1194. WANG CH H,DAI L,et al.. Investigation on laser-induced breakdown spectroscopy of AlCl₃ water solution[J]. Chinese J. Lasers,2006,33(9):1190-1194.(in Chinese) [35] ESELLER K E,YUEH F Y,SINGH J P. Non-intrusive, on-line, simultaneous multi-species impurity monitoring in hydrogen using LIBS[J]. Appl Phys B,2011,102:963-969. [36] GALLOU G,SIRVEN J B,DUTOUQUET C,et al.. Aerosols analysis by LIBS for monitoring of air pollution by industrial sources[J]. Aerosol Science and Technology,2011,45:918-926. [37] LAZIC V,COLAO F,FANTONI R,et al.. Underwater sediment analyses by laser induced breakdown spectroscopy and calibration procedure for fluctuating plasma parameters[J]. Spectrochimica Acta Part B,2007,62:30-39. [38] BEDDOWS D C S TELLE H H. Prospects of real-time single-particle biological aerosol analysis:a comparison between laser-induced breakdown spectroscopy and aerosol time-of-flight mass spectrometry[J]. Spectrochimica Acta Part B,2005,60:1040-1059. [39] DIXON P B. HAHN D W. Feasibility of detection and identification of individual Bioaerosols using laser-induced breakdown spectroscopy[J]. Anal. Chem.,2005,77:631-638 [40] 张大成,马新文,等. 激光诱导击穿光谱应用于三种水果样品微量元素的分析[J]. 物理学报,2008,57:6348-6353. ZHANG D C,MA X W,et al.. Application of laser-induced breakdown spectroscopy in analyzing microelements in three kinds of fruit samples[J]. Acta Physica Sinica,2008,57:6348-6353.(in Chinese) [41] 卢伟业,陆继东,姚顺春,等. 复合肥氮磷钾元素含量的激光诱导击穿光谱同步测量[J]. 中国激光,2011,38(10):169:174. LU W Y,LU J D,YAO SH CH,et al.. Synchronization detection of nitrogen phosphorus potassium in compound fertilizer with laser induced breakdown spectroscopy[J]. Chinese J. Lasers,2011,38(10):169-174.(in Chinese) [42] RAI N P,RAI S G,BICANIC D. Application of LIBS in detection of antihyperglycemic trace elements in Momordica charantia[J]. Food Biophysics,2009,4:167-171. [43] MATTHIEU B,LAURENT G,JIN Y,et al.. Spectral signature of native CN bonds for bacterium detection and identification using femtosecond laser-induced breakdown spectroscopy[J]. Appl. Phys. Lett.,2006,88(6):063901. [44] SAMEK O,BEDDOUS D C,TELLE H H,et al.. Quantitative laser-induced breakdown spectroscopy analysis of calcified tissue samples[J]. Spectrochoimica Acta Part B,2001,56(6):865-875. [45] PEDRINI G,FRONING P,TINIANE H J,et al.. Shape measurement of microscopic structure using digital holograms[J]. Opt. Commun.,1999,164:257-268. [46] 刘宪云,王振亚,郝立庆. 激光诱导击穿光谱在生物医学中的应用[J]. 激光技术,2008,32:134-136 LIU X Y,WANG ZH Y,HAO L Q. Application of laser induced breakdown spectroscopy technology in biomedicine field[J]. Laser Technology,2008,32:134-136.(in Chinese) [47] 吴金泉,林兆祥,等. 藏药七十味珍珠丸的激光诱导击穿光谱检测[J]. 中南民族大学学报(自然科学版),2009,28(2):53-56. WU J Q,LIN ZH X,et al.. Determination Tibetan medicine of the 70 Pearl Flavor Pill by Laser-Induced Breakdown Spectroscopy[J]. J. South-central University for Nationalities,2009,28(2):53-56.(in Chinese) [48] 陆运章,汪家升,乔东坡,等. 激光诱导击穿光谱法分析不锈钢中金属元素[J]. 冶金分析,2010,30(7):10-15. LU Y ZH,WANG J S,QIAO D P,et al.. Analysis of metal elements in stainless steel by using laser-induced breakdown spectroscopy[J]. Metallurgical Analysis,2010,30(7):10-15.(in Chinese) [49] DEATH D L,CUNNINGHAM A P,POLLARD I. J. Multi-element analysis of iron ore pellets by Laser-induced Breakdown Spectroscopy and principal components regression[J]. Spectrochim. Acta,Part B,2008,63:763-769. [50] TAWFIK W,MOHAMED Y. Improved LIBS limit of detection of Be, Mg, Si, Mn, Fe and Cu inaluminum alloy samples using a portable Echelle spectrometer with ICCD camera[J]. Optics Laser Technology,2008,40:30-38. [51] HARMON R S,DELUCIA F C J,LAPOINTE A,et al.. LIBS for landmine detection and discrimination[J]. Anal. Bioanal. Chem.,2006,385:1140-1148. [52] SALIE B,LACOUR J L,MAUCHIEN P,et al.. Comparative study of different methodologies for quantitative rock analysis by Laser-Induced breakdown spectroscopy in a simulated Martian atmosphere[J]. Spectrochim. Acta B,2006,61(3):301-313.

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