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Li+, Zn2+, Mg2+掺杂Lu2O3:Er3+荧光粉的制备及发光特性

王林香 庹娟 叶颖 赵海琴

王林香, 庹娟, 叶颖, 赵海琴. Li+, Zn2+, Mg2+掺杂Lu2O3:Er3+荧光粉的制备及发光特性[J]. 中国光学(中英文), 2019, 12(1): 112-121. doi: 10.3788/CO.20191201.0112
引用本文: 王林香, 庹娟, 叶颖, 赵海琴. Li+, Zn2+, Mg2+掺杂Lu2O3:Er3+荧光粉的制备及发光特性[J]. 中国光学(中英文), 2019, 12(1): 112-121. doi: 10.3788/CO.20191201.0112
WANG Lin-xiang, TUO Juan, YE Ying, ZHAO Hai-qin. Preparation and luminescence properties of Li+, Zn2+, Mg2+ doped Lu2O3: Er3+ phosphors[J]. Chinese Optics, 2019, 12(1): 112-121. doi: 10.3788/CO.20191201.0112
Citation: WANG Lin-xiang, TUO Juan, YE Ying, ZHAO Hai-qin. Preparation and luminescence properties of Li+, Zn2+, Mg2+ doped Lu2O3: Er3+ phosphors[J]. Chinese Optics, 2019, 12(1): 112-121. doi: 10.3788/CO.20191201.0112

Li+, Zn2+, Mg2+掺杂Lu2O3:Er3+荧光粉的制备及发光特性

doi: 10.3788/CO.20191201.0112
基金项目: 

新疆维吾尔自治区自然科学基金 2017D01A60

新疆师范大学新型光源与微纳光学重点实验室项目 XJNUSYS092018B06

详细信息
    作者简介:

    王林香(1979-), 女, 甘肃秦安人, 博士, 副教授, 2010年于中国科学技术大学获得博士学位, 主要从事纳米发光材料方面的研究。E-mail:wanglinxiang23@126.com

  • 中图分类号: O614.3;TQ17

Preparation and luminescence properties of Li+, Zn2+, Mg2+ doped Lu2O3: Er3+ phosphors

Funds: 

Natrural Science Foundation of Xinjiang, China 2017D01A60

Foundation of Xinjiang Normal University Laboratory of Novel Light Source and Micro/Nano-Optics, China XJNUSYS092018B06

More Information
  • 摘要: 用微波高温固相法合成了Er3+单掺Lu2O3,Li+与Er3+共掺Lu2O3及Li+,Zn2+,Mg2+掺杂Lu2O3:Er3+的荧光粉。实验表明金属离子Li+、Zn2+、Mg2+、Er3+掺杂Lu2O3,不影响Lu2O3的立方晶相。扫描电子显微镜测量表明,Li+掺杂可以有效改善粉体的分散性和形貌,Li+,Zn2+,Mg2+共掺杂获得的粉体颗粒分布更加均匀,粒径范围为80~100 nm。379 nm激发下,Li+与Er3+共掺样品发光较单掺Er3+样品在565 nm处的发光增强了4.5倍,而Li+、Zn2+、Mg2+与Er3+共掺样品较其发光增强5.3倍。980 nm激发下,Li+与Er3+共掺样品,Li+、Zn2+、Mg2+与Er3+共掺样品的发光分别比单掺Er3+样品在565 nm处发光增强23倍与39倍,在662 nm处发光强度分别增强20倍与43倍。379 nm激发下,较单掺Er3+的样品,掺杂Li+的样品和Li+,Zn2+,Mg2+和Er3+共掺的样品荧光寿命均有所增加,而Zn2+、Er3+共掺及Mg2+、Er3+共掺样品的荧光寿命则有所缩短。

     

  • 图 1  Li+, Zn2+, Mg2+掺杂Lu2O3:Er3+样品的XRD图

    Figure 1.  X-ray diffraction patterns of Lu2O3:Er3+ doped with Li+, Zn2+ and Mg2+ at different concentrations

    图 2  样品的SEM照片

    Figure 2.  Nanocrystalline SEM photos of No.2, No.6, No.11 samples

    图 3  Lu2O3:Er3+的激发光谱(a)及发射光谱(b)

    Figure 3.  Excitation(a) and emission spectra(b) of Lu2O3:Er3+ sample

    图 4  不同浓度Li+和Er3+共掺Lu2O3的激发光谱(a)和发射光谱(b)

    Figure 4.  Excitation(a) and emission spectra(b) of Lu2O3 samples co-doped with Li+ and Er3+

    图 5  Li+, Zn2+, Mg2+和Er3+共掺Lu2O3的激发光谱(a)和发射光谱(b)

    Figure 5.  Excitation(a) and emission spectra(b) of Li+, Zn2+, Mg2+co-doped Lu2O3:Er3+ samples

    图 6  980 nm激发下Li+, Zn2+, Mg2+, Er3+共掺Lu2O3的荧光粉的发射谱

    Figure 6.  Up-conversion emission spectra of Li+, Zn2+, Mg2+doped Lu2O3:Er3+ samples

    图 7  379 nm激发下Li+、Zn2+、Mg2+和Er3+共掺Lu2O3的荧光衰减曲线

    Figure 7.  Fluorescence decay curves of Li+, Zn2+, Mg2+ doped Lu2O3:Er3+ samples(λex=379 nm)

    表  1  不同浓度(摩尔质量百分比)Li+, Zn2+, Mg2+掺杂Lu2O3:Er3+样品

    Table  1.   Lu2O3:Er3+ doped with Li+, Zn2+ and Mg2+ at different concentrations

    Sample Er3+/% Li3+/% Zn2+/% Mg2+/% Lu2O3/%
    1 1 0 0 0 99
    2 2 0 0 0 98
    3 5 0 0 0 95
    4 2 1 0 0 97
    5 2 3 0 0 95
    6 2 5 0 0 93
    7 2 8 0 0 90
    8 2 12 0 0 86
    9 2 0 5 0 93
    10 2 0 0 5 93
    11 2 5 2.5 2.5 88
    下载: 导出CSV

    表  2  Li+, Zn2+, Mg2+掺杂Lu2O3 :Er3+样品的寿命

    Table  2.   Lifetime of Li+, Zn2+, Mg2+ doped Lu2O3:Er3+ samples

    λex/nm Energy level Sample 2 4 5 6 7
    lifetime/μs 51.366 9 55.281 9 61.408 5 63.623 1 61.908 8
    379 4S3/24I15/2 Sample 8 9 10 11
    lifetime/μs 61.289 5 44.300 7 42.958 8 61.672 5
    下载: 导出CSV
  • [1] 王鹏贺, 王能利, 张希艳, 等.碳酸盐共沉淀法合成Lu2O3:Er3+纳米粉体及性能表征[J].无机化学学报, 2012, 28(11):2335-2340. http://d.old.wanfangdata.com.cn/Periodical/wjhxxb201211010

    WANG P H, WANG N L, ZHANG X Y, et al.. Carbonate co-precipitation synthesis of Lu2O3:Er3+ nano-powders and its property characterization[J]. Chinese Journal of Inorganic Chemistry, 2012, 28(11):2335-2340.(in Chinese) http://d.old.wanfangdata.com.cn/Periodical/wjhxxb201211010
    [2] 庹娟, 王林香, 叶颖, 等.金属离子Li+, Na+, K+, Ca2+, Ba2+掺杂Lu2O3:Pr3+荧光粉的制备及发光特性研究[J].发光学报, 2018, 39(3):307-314.

    TUO J, WANG L X, YE Y, et al.. Preparation and luminescence properties of Lu2O3:Pr3+ phosphors codoped with Li+, Na+, K+, Ca2+, Ba2+ ions[J]. Chinese Journal of Luminescence, 2018, 39(3):307-314.(in Chinese)
    [3] CHEN G Y, LIANG H J, LIU H C, et al.. Anomalous power dependence of upconversion emissions in Gd2O3:Er3+ nanocrystals[J]. Journal of Applied Physics, 2009, 105:1-5.
    [4] 肖思国, 阳效良, 丁建文.Er3+, Er3+/Yb3+掺杂氟化镧超微材料的光谱特性与上转换发光[J].物理学报, 2009, 58(6):3812-3820. doi: 10.3321/j.issn:1000-3290.2009.06.033

    XIAO S G, YANG X L, DING J W. Luminescence properties and upconversion of Er3+ doped and Er3+/Yb3+ co-doped LaF3 particles[J]. Acta Physica Sinica, 2009, 58(6):3812-3820.(in Chinese) doi: 10.3321/j.issn:1000-3290.2009.06.033
    [5] 王鹏贺.Er3+: Lu2O3纳米粉体和透明陶瓷的制备及光谱性质研究[D].长春: 长春理工大学, 2011.

    WANG P H. Preparation and spectroscopic properties of Er3+: Lu2O3 nano powders and transparent ceramics[D]. Changchun: Changchun University of Science and Technology, 2011.(in Chinese)
    [6] LI T, BEIL K, KRNKEL C, et al.. Efficient high-power continuous wave Er:Lu2O3 laser at 2.85μm[J]. Optics Letters, 2012, 37(13):2568-2570. doi: 10.1364/OL.37.002568
    [7] 刘禄.Er3+/Yb3+/Li+掺杂氧化物纳米晶上转换荧光机制及应用研究[D].哈尔滨: 哈尔滨工业大学, 2011.

    LIU L. Upconversion mechanisms of Er3+/Yb3+/Li+ doped oxde nanocrystals and their applications[D]. Harbin: Harbin Institute of Technology, 2011.(in Chinese)
    [8] 徐赛.LD泵浦3微米Er固体激光器输出特性研究[D].哈尔滨: 哈尔滨工业大学, 2015.

    XU S. Studies on output performance of 3 micron band Er-doped solid state lasers pumped by LD[D]. Harbin: Harbin Institute of Technology, 2015.(in Chinese)
    [9] 李玮楠, 邹快盛, 陆敏, 等.掺Er3+硅酸盐玻璃上转换发光特性研究[J].无机材料学报, 2007, 22(1):30-34. doi: 10.3321/j.issn:1000-324X.2007.01.006

    LI W N, ZOU K SH, LU M, et al.. Properties of up-conversion emission of Er3+ doped silicate glasses[J]. Journal of Inorganic Materials, 2007, 22(1):30-34. (in Chinese) doi: 10.3321/j.issn:1000-324X.2007.01.006
    [10] 李艳平.稀土激活的LuBO3、Lu2O3纳米材料的制备与发光性质[D].长春: 长春光学精密机械与物理研究所, 2010.

    LI Y P. Preparation and luminescence properties of LuBO3 and Lu2O3 nanomaterials activated by rare earth ions[D]. Changchun: Changchun Institute of Optics, Fine Mechanics and Physics, 2010.(in Chinese)
    [11] 徐斌, 周勇强, 王荷, 等.Er3+掺杂钇稳定氧化锆的上转换发光[J].光谱学与光谱分析, 2014, 34(12):3214-3217. doi: 10.3964/j.issn.1000-0593(2014)12-3214-04

    XU B, ZHOU Y Q, WANG H, et al.. Upconversion luminescence of Er3+ doped Yttrium-stabilized Zirconia powders[J]. Spectroscopy and Spectral Analysis, 2014, 34(12):3214-3217.(in Chinese) doi: 10.3964/j.issn.1000-0593(2014)12-3214-04
    [12] 尹玲珍.Yb3+、Er3+/Ho3+共掺杂的Lu2O3、KScF4上转换纳米晶的可控合成及发光性质研究[D].武汉: 湖南师范大学, 2015.

    YIN L ZH. Controllable synthesis and luminescent properties of Yb3+, Er3+/Ho3+ codoped Lu2O3、KScF4 up conversion nano-materials[D]. Wuhan: Hunan Normal University, 2015.(in Chinese)
    [13] 刘冰洁, 顾牡, 刘小林, 等.Li+, Zn2+共掺杂对Gd2O3; Eu3+纳米粉结构和发光性能的影响[J].中国稀土学报, 2007, 25(2):162-166. doi: 10.3321/j.issn:1000-4343.2007.02.006

    LIU B J, GU M, LIU X L, et al.. Effect of Li+ and Zn2+ co-doping on luminescent properties of Gd2O3:Eu3+ nanoparticles[J]. Journal of the Chinese Rare Earth Society, 2007, 25(2):162-166.(in Chinese) doi: 10.3321/j.issn:1000-4343.2007.02.006
    [14] 刘吉地, 王育华.Mg2+掺杂Zn2SiO4:Mn2+的溶胶-凝胶法合成及真空紫外发光特性研究[J].物理学报, 2010, 59(5):3558-3563. http://d.old.wanfangdata.com.cn/Periodical/wlxb201005100

    LIU J D, WANG Y H. Synthesis and luminescent properties of Mg2+ doped Zn2SiO4:Mn2+ phosphor under VUV excitation[J]. Acta Physica Sinica, 2010, 59(5):3558-3563.(in Chinese) http://d.old.wanfangdata.com.cn/Periodical/wlxb201005100
    [15] 杨英, 陈永杰, 肖林久, 等.Sr3B2O6:Eu3+, Li+荧光粉的合成与发光性能[J].发光学报, 2014, 35(3):317-321. http://d.old.wanfangdata.com.cn/Periodical/fgxb201110003

    YANG Y, CHEN Y J, XIAO L J, et al.. Synthesis and luminescent properties of Sr3B2O6:Eu3+, Li+ phosphor[J]. Chinese Journal of Luminescence, 2014, 35(3):317-321.(in Chinese). http://d.old.wanfangdata.com.cn/Periodical/fgxb201110003
    [16] 庹娟, 王林香, 李敏.Li+、Na+和Eu3+共掺Lu2O3的制备及发光特性研究[J].发光学报, 2016, 37(1):28-32. http://d.old.wanfangdata.com.cn/Periodical/fgxb201601005

    TUO J, WANG L X, LI M. Preparation and luminescence properties of Li+, Na+ and Eu3+ co-doped Lu2O3[J]. Chinese Journal of Luminescence, 2016, 37(1):28-32.(in Chinese) http://d.old.wanfangdata.com.cn/Periodical/fgxb201601005
    [17] SERIVALSATIT K, WASANAPIARNPONG T, KUCERA C, et al.. Synthesis of Er-doped Lu2O3 nanoparticles and transparent ceramics[J]. Optical Materials, 2013, 35(7):1426-1430. doi: 10.1016/j.optmat.2013.02.013
    [18] 王林香.合成条件对(Eu0.045Li3xLuy)2O3纳米晶发光性能影响[J].光学学报, 2016, 36(3):35-42.

    WANG L X. Luminescent properties of (Eu0.045Li3xLuy)2O3 nanocrystals by precipitation[J]. Acta Optica Sinica, 2016, 36(3):35-42.(in Chinese)
    [19] LI W, LEE J. Microwave-assisted sol-gel synthesis and photo-luminescence characterization of LaPO4:Eu3+, Li+ nanophosphors[J]. Journal of Physical Chemistry C, 2008, 112(31):11679-11684. doi: 10.1021/jp800101d
    [20] 郑贤火.非稀土金属离子掺杂对氧化钇粉末荧光性能的影响[D].杭州: 浙江理工大学, 2016.

    ZHEN X H. Effects of non-rare-earth metal ions doping on the fluorescent properties of yttrium oxide powder[D]. Hangzhou: Zhejiang Sci-Technology University, 2016.(in Chinese)
    [21] STUDENIKIN S A, NGOLEGO N, COCIVERA M. Fabrication of green and orange photoluminescent, undoped ZnO films using spray pyrolysis[J]. J. Appl. Phys., 1998, 84:2287. doi: 10.1063/1.368295
    [22] 徐会兵, 庄卫东, 胡运生, 等.碱金属离子掺杂对(Y, Gd)BO3: Tb绿色荧光粉性能的影响[C].2010年全国冶金物理化学学术会议论文集, 2010: 268-272.

    XU H B, ZHUANG W D, HU Y SH, et al.. Influence of alkaline metal ions doping on properties of (Y, Gd)BO3: Tb[C]. Proceedings of the national conference on metallurgy and physical chemistry in 2010, 2010, 268-272.(in Chinese)
    [23] 王林香, 李敏, 庹娟.沉淀法制备(Eu0.045Li3xNa3yGdz/Luw)2O3纳米晶及发光性能研究[J].人工晶体学报, 2015, 44(12):3671-3675. doi: 10.3969/j.issn.1000-985X.2015.12.055

    WANG L X, LI M, TUO J. Luminescent properties of (Eu0.045Li3xNa3yGdz/Luw)2O3 nanocrystals by precipitation[J]. Journal of Synthetic Cryatals, 2015, 44(12):3671-3675.(in Chinese) doi: 10.3969/j.issn.1000-985X.2015.12.055
    [24] 李小女.Er3+, Na+, CaF2透明陶瓷的制备及性能研究[D].武汉: 武汉理工大学, 2012.

    LI X N. Study on preparation and properties of Er3+, Na+ codoping CaF2 transparent ceramics[D]. Wuhan: Wuhan University of Technology, 2012.(in Chinese)
    [25] BACHIR S, AZUMA K, KOSSANYI J, et al.. Photoluminescence of polycrystalline zinc oxide co-activated with trivalent rare earth ions and lithium. Insertion of rare-earth ions into zinc oxide[J]. J. Lumin., 1997, 75:35-49. doi: 10.1016/S0022-2313(97)00093-8
    [26] WANG J, ZHANG H R, LIU Y L, et al.. Insights into luminescence quenching and detecting trap distribution in Ba2Si5N8:Eu2+ phosphor with comprehensive considerations of temperature dependent luminescence behaviors[J]. Journal of Materials Chemistry C, 2015, 3(37):9572-9579. doi: 10.1039/C5TC01849H
    [27] XIA Z G, MIAO S H, CHEN M Y, et al.. Structure, crystal lographic sites and tunable luminescence properties of Eu2+ and Ce3+/Li+ activated Ca1.65Sr0.35SiO4 phosphors[J]. Inorganic Chemistry, 2015, 54(16):7684-7691. doi: 10.1021/acs.inorgchem.5b00455
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  • 收稿日期:  2018-03-20
  • 修回日期:  2018-04-19
  • 刊出日期:  2019-02-01

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